نتایج جستجو برای: setereoselective polymerization
تعداد نتایج: 30371 فیلتر نتایج به سال:
A variety of contractile stimuli increases actin polymerization, which is essential for smooth muscle contraction. However, the mechanism(s) of actin polymerization associated with smooth muscle contraction is not fully understood. We tested the hypothesis that phosphorylated myosin triggers actin polymerization. The present study was conducted in isolated intact or beta-escin-permeabilized rat...
Heat of polymerization of Bis-GMA-TEDMA monomer mixtures, corresponding to the conceivable constituents of composite resins, was evaluated from the area of exothermic peak in DSC curves, and also the conversions of polymerization were calculated from the ratio of the heat of polymerization for each monomer mixture to an assumed one at 100% conversion. The effects of composition of monomers and ...
Cellulose was modified by polystyrene (PS) and polyacrylonitrile (PAN) via free radical and living radical polymerization, and then cellulose was used as the matrix in the preparation of polymer/clay nanocomposite, through a solution intercalation method. For this purpose, first, the graft polymerization of styrene (St) onto cellulose fibers was performed by using suspension polymerization and ...
a series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization,by coupling the allylated a-diimine complexes of the metals ti, zr, v, ni and pd with the ansa-zirconocenecomplex [c5h4-sih(me)-c5h4]zrcl2 possessing a hydride silane moiety. the different stages of syntheses includedthe formation of bis(cyclopentadienide)methyl silane which was util...
The two-dimensional polymerization and reaction at the solid/liquid interface has caused considerable attention in recent years because of its fundamental importance and many potential applications. Scanning tunneling microscopy (STM) provides the possibility for the observation and manipulation of polymerization and reaction occurring at the solid/liquid interface at the atomic level. Two-dime...
“A living race” – polymerization kinetics of anionic polymerizations depends strongly on the solvent polarity and reactivity of the growing chain end. Both the carband oxyanionic polymerization is under control at the university lab and on the industrial level, however, no information for the aza-anionic polymerization of aziridines has been reported systematically. This work studies the polyme...
The focus of this work was to improve the aqueous emulsion polymerization of a highly water-insoluble monomer derived from plant oil, acrylated methyl oleate. Conventional emulsion polymerization requires excessive amounts of surfactant and long reaction time. Miniemulsion polymerization improved the polymerization significantly. Only a fraction of the surfactant and reaction time that was nece...
The use of UHMWPE has attracted the attention of many researchers and industries. The aim of the present work is to fabricate UHMWPE/MoS2-Oxide nano-composites using in-situ polymerization. For this purpose, modified molybdenum disulfide was used. In order to perform the polymerization, a Ziegler-Natta catalytic system, with MoS2-Oxide and magnesium Ethoxide as support, was used. In order to fa...
A novel imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalyst for ethylene and ethylene/1-hexene polymerization is investigated. The catalyst is prepared by modification of (SiO2/MgO/MgCl2)TiClx Ziegler-Natta catalysts via supporting vanadium species followed by reaction with p-tolyl isocyanate as imido agents, to get the merits from both the SiO2-supported imido vanadium catalyst and the ...
The induction of variable disulfide polymerization of IgM in the trout (Oncorhynchus mykiss) and its effect on its half-life were examined. An association between greater Ab affinity and increased disulfide polymerization was first indicated by the observation of this increased IgM disulfide polymerization during the process of affinity maturation. A direct association between Ab affinity and d...
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