in this study, the fluorogenic efficiency of fluorescamine for spectrofluorimetric analysis of primary amines was investigated. different mixtures of dichloromethane and other organic solvents were used for evaluation of fluorescence stability and intensity of fluorescamine derivative (pyrrolinone). solvents such as acetonitrile (acn), tetrahydrofuran (thf) and dioxane increase stability and in...

a simple and rapid microextraction procedure based on the application of magnetic nanoparticles and hydrophobic 1-hexylpyridinium hexafluorophosphate [hpy][pf6] ionic liquid (il) was applied to trace determination of gatifloxacin. a mixture of [hpy][pf6] and magnetic nanoparticles was injected into the sample solution containing the analyse of interest and a cloudy solution was formed. after ce...

A method for the determination of trace amounts of ofloxacin has been developed, based on solid-phase spectrofluorimetry. The relative fluorescence intensity of ofloxacin fixed on Sephadex SP C-25 gel was measured directly after packing the gel beads in a 1-mm silica cell, using a solid-phase attachment. The wavelengths of excitation and emission were 294 and 494 nm, respectively. The linear co...

The potential of variable angle synchronous spectroscopy (VASS) for fluorescent mixtures resolution was assessed and compared with the rank annihilation method (RAM). For this purpose, a set of excitation-emission matrices from three standard cyclodextrin fluorescence-enhanced solutions of the pesticides aminocarb, carbendazim and coumatetralyl and a mixture of them was obtained. Careful select...


An investigation of light scattering of non-imprinted poly methacrylic acid-co-ethylene glycol dimethacrylate (PMAA-co-EGDMA) submicron particles (300±5 nm) in aqueous suspension before and after 17β-estradiol (E2) binding was conducted by using a spectrofluorimeter. An optimal excitation wavelength to determine Mie scattering from these submicron particles was 725±1 nm for the highest intensi...

The application of chelate reactions in a general way began a few years before the turn of the century, but the term 'chelate' was coined considerably later by Morgan and his colleagues at the University of Birmingham, who made the first systematic studies. Work in this field has continued at Birmingham for over half a century, apart from a break during the war years. During the last twenty-fiv...

• Abstract: Seawater from 8 stations in Admiralty Bay was systematically sampled during the summer of 1994, 1995, 1996 and 1997 and analyzed by spectrofluorimetry to measure dissolved/dispersed petroleum hydrocarbons (DDPHs). The purpose of this study was to detect some temporal and spatial changes in terms of oil contamination of the region. The results indicate low levels of oil pollution wit...

A simple and rapid microextraction procedure based on the application of magnetic nanoparticles and hydrophobic 1-Hexylpyridinium hexafluorophosphate [Hpy][PF6] ionic liquid (IL) was applied to trace determination of gatifloxacin. A mixture of [Hpy][PF6] and magnetic nanoparticles was injected into the sample solution containing the analyse of interest and a cloudy solution was forme...