By the use of wavelength-modulation diode laser spectroscopy, water vapor and oxygen are detected in scattering media nonintrusively, at 980 nm and 760 nm, respectively. The technique demonstrated is based on the fact that free gases have extremely sharp absorption structures in comparison with the broad features of bulk material. Water vapor and oxygen measurements have been performed during t...

The role of FTIR speetroscopy in catalytic studies is briefly discussed and some typical examples are shown. IR spectra of weakly bound hydrogen on PtjSi02 reveal surface heterogeneity; The hydrogen concentration on the surface is described by a Temkin isotherm. Adsorption of unsaturated C6 ring compounds on hydrogen poor PtjSi02 is essentially a self'-hydrogenation process resulting in the for...