In this work, solid solutions of La 0.7 Sr 0.3 Mn 0.9 5Fe 0.05 O 3-δ with different oxygen content were obtained by the solid-phase reactions technique. Based on investigation dynamics changes in index (3 – δ) during heating samples, formation a stressed state their grains as result annealing was established. This results decrease mobility vacancies reduction cations according to 4+ + e → 3+ sc...