Recent developments in small-angle neutron scattering (SANS) investigations on polymer gels are reviewed by encompassing (i) volume phase transition and microphase separation, (ii) inhomogeneities in polymer gels, (iii) pressure dependence of hydrophobic interaction and (iv) structural characterization of super-tough gels. These developments owe much to the understanding of gel inhomogeneities ...

Various nanoparticles (silicon oxide, tin oxide and aluminium oxide) were mixed with poly (methyl siloxane) (Rhodorsil 224). The mixtures were sprayed on silicon substrates resulting in the formation of a rough, two-length-scaled hierarchical structure surface layer. We report that: (i) Super-hydrophobic composite films were produced with all the particles used, (ii) The effect of the particle’...

Hydrophobic surfaces can allow a liquid to slip over the surface and thus reduce friction in lubricated contact working full film regime. Theory supports that amount of be increased if super-hydrophobic are composed textured low energy material used. In this work, polytetrafluoroethylene (PTFE) polymer samples were with femto second laser create by machining hexagonal network small circular hol...

Abstract Super-hydrophobic textured surfaces reduce hydrodynamic drag in pressure-driven laminar flows micro-channels. However, despite the wide usage of non-Newtonian liquids microfluidic devices, flow behaviour such was rarely examined so far context friction reduction super-hydrophobic Thus, we have investigated influence topologically different rough on shear-thinning First, factor ratio (a...

This paper describes a simple and low-cost fabrication method for multi-functional nanostructures with outstanding anti-reflective and super-hydrophobic properties. Our method employed phase separation of a metal salt-polymer nanocomposite film that leads to nanoisland formation after etching away the polymer matrix, and the metal salt island can then be utilized as a hard mask for dry etching ...

The interaction between two associating hydrophobic particles has traditionally been explained in terms of the release of entropically frustrated hydration shell water molecules. However, this picture cannot account for the kinetics of hydrophobic association and is therefore not capable of providing a microscopic description of the hydrophobic interaction (HI). Here, Monte Carlo simulations of...

The principles obtained from studies on molecular chaperones have provided explanations for the assisted protein folding in vivo. However, the majority of proteins can fold without the assistance of the known molecular chaperones, and little attention has been paid to the potential chaperoning roles of other macromolecules. During protein biogenesis and folding, newly synthesized polypeptide ch...

In the present work, we have explored the use of the triphenylmethyl group, a commonly used protecting group for primary alcohols as a gelling structural component in the design of molecular gelators. We synthesized a small library of triphenylmethyl derivatives of simple primary alcohols and studied their gelation properties in different solvents. Gelation efficiency for some of the derivative...

Magnesian limestone is a key construction component of many historic buildings that is under constant attack from environmental pollutants notably by oxides of sulfur via acid rain, particulate matter sulfate and gaseous SO(2) emissions. Hydrophobic surface coatings offer a potential route to protect existing stonework in cultural heritage sites, however, many available coatings act by blocking...