a quantum chemical study of the corrosion inhibition properties of some organic inhibitormolecules, pyridine, 2-picoline, 3-picoline, 4-picoline, 2, 4-lutidine at the aluminum surface inhydrochloric acid (hcl) was carried out. the models of the inhibitors adsorption on the al-surfacewere optimized with the hf and b3lyp level using the 6-31g and lanl2dz basis sets fromthe program package gaussia...

In this paper a transient free convection flow around a sphere with variable surface temperature and embedded in a porous medium has been considered. The temperature of the sphere is suddenly raised and subsequently maintained at values that varies with position on surface. The method of asymptotic expansions is applied for small Rayleigh numbers and then a finite-difference scheme is used to s...

In this paper, a general elastoplastic-damage constitutive model considering the effect of strain rate has been developed. The derivation of this model has been cast into the irreversible thermodynamics with internal variables within the fundamentals of Continuum Damage Mechanics (CDM). The rate effect has been involved as an additional term into the plastic yield surface (dynamic plastic yield...

In this paper, CuO nanoparticles  have been synthesized via solid- state thermal decomposition using copper(II) Schiff base complexes as new precursors at 600ºC under air atmosphere for 3 h. Surface morphology of the products were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and scanning electron microscopy (SEM).

microcantilevers (mcls) are cost-effective and highly sensitive devices for biodetection. adsorption of specific analytes on the microcantilever surface causes the bending of mcl through changing of the surface characteristics. these new bioprobes designed in a way that one side of the microcantilever surface is coated with a selective receptor that absorbs particular molecules. after surface a...