A thermodynamic study of copper ions by jack bean urease (JBU) was carried out at two temperatures of 27 and 37?C in Tris buffer (30 mM; pH=7.0) using an isothermal titration calorimetry. There is a set of twelve identical and non-interacting binding sites for copper ions. The intrinsic dissociation equilibrium constant and the molar enthalpy of binding are 285 µM and ?15.2 kJ/mol at 27?C and 3...

The thermodynamic model of ultrathin lubricant lm melting conned between two atomically-at solid surfaces is built using the Landau phase transition approach. Non-equilibrium entropy is introduced describing the part of thermal motion conditioned by non-equilibrium and non-homogeneous character of the thermal distribution. The equilibrium entropy is changed during time due to transition of non-...

The traditional theory for binary homogeneous nucleation follows the classical derivation of the nucleation rate in the supposition of a hypothetical constrained-equilibrium distribution in the calculation of the cluster evaporation rate. This model enables calculation of the nucleation rate, but requires evaluation of the cluster distribution and cluster properties for an unstable equilibrium ...

Microbially mediated terminal electron accepting processes (TEAPs) to a large extent control the fate of redox reactive elements and associated reactions in anoxic soils, sediments, and aquifers. This review focuses on thermodynamic controls and regulation of H2-dependent TEAPs, case studies illustrating this concept, and the quantitative description of thermodynamic controls in modeling. Other...

The liquid-gas phase transition in finite nuclei is studied in a heated liquid-drop model where the drop is assumed to be in thermodynamic equilibrium with the vapour emanated from it. Changing pressure along the liquid-gas coexistence line of the systems, symmetric or asymmetric, suggests that the phase transition is a continuous one. This is further corroborated from the study of the thermal ...

In this research, the activity of MnO, produced during steel making in aluminate-rich slags, was investigated. According to thermodynamic equations and mathematical calculation, a series of relations was obtained for evaluation of oxide activity using Masson’s theory. The obtained relations were solved according to Levenberg- Marquardt method and using Matlab software. The results were correlat...

A binding study of nickel ions by a new recombinant human Growth Hormone (hGH), produced as an injected drug, has been done at 27˚C in NaCl solution (50 mM) using an isothermal titration calorimetry. There is a set of three identical and non-interacting binding sites for nickel ions. The intrinsic dissociation equilibrium constant and the molar enthalpy of binding are 40 μM and -16...