Photocatalytic membrane was successfully prepared using an efficiently high surface area TiO2 catalyst, dispersed into polyacrylonitrile matrix. The catalyst was directly synthesized using titanium triisopropanolamine as a precursor. The membranes were characterized using FT-IR, TGA, SEM and their photocatalytic performance tested, viz. stability, permeate flux and photocatalytic degradation of...

Fish scale (FS) loaded TiO2 composites were investigated as photocatalysts in degradation of Methyl Orange under solar light irradiation. Composites were prepared through sol-gel method by varying mass ratio of TiO2/FS at 90:10, 70:30 and 50:50, respectively. The catalysts prepared in this study were characterized by using XRD, SEM, FT-IR and nitrogen sorption. The effects of solar irradiation,...

Composites consisting of carbon nanotubes (CNTs) grown directly on oxygen-deficient anatase TiO2 (TiO2−δ) were synthesized by a two-step chemical vapor deposition (CVD) method and applied in photocatalytic hydrogen production from aqueous methanol solutions using photodeposited Pt as the co-catalyst. Thermogravimetry coupled with mass spectroscopy, X-ray diffraction, scanning electron microscop...

The photocatalytic activity of phosphonated Re complexes, [Re(2,2'-bipyridine-4,4'-bisphosphonic acid) (CO)3(L)] (ReP; L = 3-picoline or bromide) immobilised on TiO2 nanoparticles is reported. The heterogenised Re catalyst on the semiconductor, ReP-TiO2 hybrid, displays an improvement in CO2 reduction photocatalysis. A high turnover number (TON) of 48 molCO molRe(-1) is observed in DMF with the...

Introduction As one of the most common nanomaterials, TiO2 nanoparticles have found their industrial and household applications in cosmetics, sunscreens, pharmacy, socks, paints and coatings, catalyst, even food and many other fields, which are expected to continue to grow in the next decade [1]. However, the release of TiO2 nanoparticles into the aquatic environment is inevitable during the pr...

Pt/TiO2, Ce/TiO2 and binary system PtCe/TiO2 catalysts were prepared by impregnation method and the structural properties of these catalysts were investigated by means of XRD, CO-TPD and UV-vis diffuse reflectance spectroscopy. As investigated by XRD, the composition of the prepared samples anatase and rutile phases with higher amount of anatase phase and its particle size was in the range of 1...

The photocatalytic degradation of organic compounds of olive mill wastewater (OMWW) was investigated by using core-shell-shell Fe3O4/SiO2/TiO2 nanoparticles as catalyst. The preparation of nanoparticles was performed by coating onto magnetic nanoparticles a SiO2 layer, using Stober method and TiO2 layer, using sol-gel method. The photo catalyst was characterized by dynamic light scattering (DLS...

This research focused on the preparation and characterization of Cu@N-TiO2/Ti (N-TiO2/Ti decorated with Cu) thin film electrode and its activities test in photoelectrocatalytic system. This study investigated the time effect of Copper (Cu) electrodeposition and the concentration of nitrogen (N) in the photocatalytic characteristics of TiO2. The catalyst has been prepared for activities test on ...

A hybrid carbon fiber electrode (CFE) consisting of TiO2 semiconductor photocatalyst and Pt-Ru catalyst has been developed to boost the performance of direct methanol fuel cells (DMFC). These two catalyst nanoparticles are deposited on opposite sides of the carbon fiber paper such that methanol oxidation is carried out catalytically on Pt-Ru and photocatalytically on TiO2 under UV-light irradia...

This study first presents a "TiO2-based eco-catalyst" working in the dark and under visible-light irradiation for the degradation of environmental organic pollutants. Molecular scale cobalt(III) oxide clusters are formed on the surface of highly active anatase TiO2 nanoparticles (Co2O3-TiO2) by the chemisorption-calcination cycle method. Co2O3-TiO2 exhibits very high visible-light activities fo...