The oxidation of alcohols to carbonyl compounds in a clean fashion (i.e., with water as a solvent or under solvent-free conditions, and using O2 or H2O2 as the primary oxidant) is the subject of considerable research efforts. A new approach for the selective oxidation of soluble aromatic alcohols in water under mild conditions via a novel composite photocatalyst has been developed. The catalyst...

titanium dioxide nanocrystals were synthesized by sol-gel method at room temperature. titanium isoprophoxide and absolute ethanol were used as precursors to prepare the sol. the ph of the solution was adjusted by adding nitric acid and sodium hydroxide solution. the prepared tio2 nanocrystals were annealed at 325°c, 425°c and 525°c respectively. the effect of ph on the surface morphology and st...

Nanosized titanium dioxide (TiO2) in its anatase form is the most frequently studied and as well as used photocatalyst. There are several syntheses procedures which enable to achieve photocatalytic TiO2. The solgel method utilizing titanium alkoxides is used most often. Alternative precursors such as titanium tetrachloride and titanyl sulphate are also frequently employed. Nowadays the environm...

The interest to nanoobjects is mainly attracted by the fact that their properties (and also biological in particular interest to the project) differ drastically from the properties of either bulk material or constituent molecules. The fundamental task is correlation between structure of the nanoparticles and their interaction with surrounding media. The aim of project is a study of interaction ...

To evaluate the significance of thin-film composite membrane surface morphology on water productivity, flat-sheet experiments were conducted with silicon dioxide, titanium dioxide, and cerium dioxide nanoparticles. The polyamide thin-film active layer exhibited a valley and ridge morphology that was directly related to the surface roughness, and was found to contribute to particle accumulation ...

Matrix-assisted laser desorption/ionization-mass spectrometry (MALDI-MS) measurements in the low-molecular-mass region, ranging from 0 to 1000 Daltons are very often difficult to perform because of signal interferences originating from matrix ions. In order to overcome this problem, a stainless steel target was coated with a homogeneous titanium dioxide layer. The layer obtained was further inv...