نتایج جستجو برای: transition metal

تعداد نتایج: 436811  

2010
Qinglei Meng

Metal Insulator transition(MIT) is characterized by the conductivity which will be zero in the insulator phase. In this term paper, we focus on Mott insulator, and a simple theoritical way to describe this MIT is the Hubbard Model .Finally, we will look at the experiments of Mott insulator transition .

2014
C. W. J. Hare

Even so, extensive research has been carried out on potential eco-toxic effects of particulate and extensively degraded oxo-biodegradable plastics when mixed with soil. Tests included seed germination and plant growth rates, compared with the same soil without degraded plastics [3,4], the effects on macro-organisms (worms, daphnia, etc.) in the soil [4] and on the accumulation of transition met...

Journal: :Physical chemistry chemical physics : PCCP 2008
Dmitry Yu Zubarev Boris B Averkiev Hua-Jin Zhai Lai-Sheng Wang Alexander I Boldyrev

Aromaticity is an important concept in chemistry primarily for organic compounds, but it has been extended to compounds containing transition-metal atoms. Recent findings of aromaticity and antiaromaticity in all-metal clusters have stimulated further research in describing the chemical bonding, structures and stability in transition-metal clusters and compounds on the basis of aromaticity and ...

2017
John G. Verkade

Homogeneous transition metal complex catalysts for organic industrial processes are converted to catalysts which are heterogeneous with respect to the reactants, and which have substantially equal catalytic activity to the homogeneous catalysts. This is done by reacting a normally homogeneous transition metal complex catalyst with a metal bridging ligand which substantially duplicates the ligan...

2005
Miwako MORI

ganic chemistry. In particular, they play an important role in carbon–carbon bond formation. A metalacycle, i.e., a ring compound containing a transition metal, is a useful intermediate in synthetic organic chemistry. Oxidative cyclization of unsaturated hydrocarbons, such as alkene, alkyne, carbonyl compounds, or nitrile, using a low-valent transition metal is a useful reaction for synthesis o...

Journal: :journal of physical & theoretical chemistry 2011
m. sayadian l. pishkar f. mollaamin

calixarenes are a readily available and important class of macrocycles in supramolecularchemistry. calixarenes have generated considerable interest due to their basket shaped structureand as useful building blocks to synthesize selective receptors for the guest species, notably alkali,alkaline earth, lanthanide and transition metal cations. in this work studied on the complexingproperties of a ...

2013
Grégory Landelle Armen Panossian Sergiy Pazenok Jean-Pierre Vors Frédéric R Leroux

In the last few years, transition metal-mediated reactions have joined the toolbox of chemists working in the field of fluorination for Life-Science oriented research. The successful execution of transition metal-catalyzed carbon-fluorine bond formation has become a landmark achievement in fluorine chemistry. This rapidly growing research field has been the subject of some excellent reviews. Ou...

2007
Ute Krämer Ina N. Talke Marc Hanikenne

Transition metal transporters are of central importance in the plant metal homeostasis network which maintains internal metal concentrations within physiological limits. An overview is given of the functions of known transition metal transporters in the context of the unique chemical properties of their substrates. The modifications of the metal homeostasis network associated with the adaptatio...

2010
Yijia Gu Jinbo Cao Junqiao Wu Long-Qing Chen

Related Articles Magnetic field modulated dielectric relaxation behavior of Pt/BiScO3-PbTiO3/La0.7Sr0.3MnO3 heterostructure in metal-insulator transition region: An equivalent-circuit method J. Appl. Phys. 110, 114118 (2011) The dynamical process of the phase transition from VO2(M) to VO2(R) J. Appl. Phys. 110, 113517 (2011) Insulator-metal transition in GeTe/Sb2Te3 multilayer induced by grain ...

1997
P Harrison

A percolation theory approach is taken to investigate electron hopping transport and the metal{non-metal transition in n-type-doped semiconductor systems. The activation energy is calculated for inter-layer hopping events in multiple-layer systems. The corresponding critical sheet density for the metal{non-metal transition is calculated, and it is shown that this increases for increasing-layer ...

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