In this work, bulk Czochralski-grown single crystals of 10 mol. % Al2O3 alloyed B-Ga2O3 - monoclinic 10% AGO or B-(Al0.1Ga0.9)2O3 are obtained, which show +0.20 eV increase in the bandgap compared with unintentionally doped B-Ga2O3. Further, growths 33% B-(Al0.33Ga0.67)2O3 and 50% B-(Al0.5Ga0.5)2O3 B-AlGaO3 produce polycrystalline single-phase material (B-AGO). All three compositions investigat...