zno and zno:mn nanocrystals synthesized via reverse micelle method. the size, band gap, urbach energy, optical constants and penetration depth of nanocrystals were calculated by uv-vis spectroscopy data. the surface morphology was studied with the use of scanning electron microscope (sem). moreover the samples exposed to gama ray source of 60co and their thermoluminescence properties were also ...

Investigations into V-agent interaction with 1,10-phenanthroline nitrate Ln(III) complexes (Eu and Tb) were carried out using luminescence and UV-Vis spectroscopy. Addition of several equivalents of agent resulted in the loss of luminescence intensity and the observation of free 1,10-phenanthroline by UV-Vis. We propose a displacement mechanism in which the V-agent acts as a bidentate ligand to...

A polyethylenimine (PEI) self-assembled monolayer (SAM) is prepared, capable of complexing silver and copper cations and of anchoring silver nanoparticles, exerting antibacterial activity against Escherichia coli and Staphylococcus aureus. Functionalized glassy surfaces have been fully characterized through spectroscopic techniques (UV-Vis spectroscopy, spectroscopic ellipsometry), atomic force...

A tetrasubstituted tetraferrocenylstannane is formed from 1-bromoferrocene-1'-carboxylic acid methyl ester and copper bronze. The molecular structure is almost perfectly tetrahedral with FeFe distances of around 6 A. In solution two sequential one-electron processes and one two-electron process are indicative of mixed-valent intermediates. Intermetallic interactions have been probed by preparat...

Since consumers are showing increased interest in the origin and method of production of their food, it is important to be able to authenticate dietary history of animals by rapid and robust methods used in the ruminant products. Promising breakthroughs have been made in the use of spectroscopic methods on fat to discriminate pasture-fed and concentrate-fed lambs. However, questions remained on...

Three derivatives of thieno[3,2-b]thiophene end-capped with phenyl units have been synthesized and characterized by MALDI TOF mass spectroscopy, elemental analysis, UV-vis absorption spectroscopy and thermogravimetric analysis (TGA). All compounds were prepared using Pd-catalyzed Stille or Suzuki coupling reactions. Optical measurements and thermal analysis revealed that these compounds are pro...

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Visible and near infrared (VIS-NIR) spectroscopy has been applied to estimate soil organic carbon (SOC) content with many modeling strategies and techniques, in which a crucial and challenging problem is to obtain accurate estimations using a limited number of samples with reference values (labeled samples). To solve such a challenging problem, this study, with Honghu City (Hubei Province, Chin...

nanocrystals of zno were prepared by microwave irradiation using zn (ii) acetate and triethanol amin (tea) as the starting materials and water as solvent. the nanocrystals of zno with hexagonal (wurtzite) structure were characterized by x-ray powder diffraction (xrd), transmission electron microscopy (tem), scanning electron microscopy (sem), uv-vis absorption and ftir spectroscopy techniques.

sol-gel derived sulfur modified and pure zno nanorod were prepared using zinc chloride and thiocarbamide as raw materials. prepared nanorods were characterized by means of x-ray diffraction (xrd), thermogravimetry- differential scanning calorimetry (tg–dsc), uv- vis absorption spectroscopy, brunauer emmett teller (bet) specific surface area and barrett joyner halenda (bjh) pore size distributio...