A simple and highly sensitive voltammetric method was developed for the determination of isoxsuprine HCl (I) and fenoterol HBr (II) in dosage forms and biological fluids. The method is based on treatment of the two compounds with nitrous acid followed by measuring the cathodic current produced by the resulting nitroso derivatives. The voltammetric behavior was studied adopting Direct Current (D...

A simple and convenient method is described for voltammetric determination of carbidopa (CD), based on its electrochemical oxidation at a modified multiwall carbon nanotube paste electrode. Under optimized conditions, the proposed method exhibited acceptable analytical performances in terms of linearity (over the concentration range from 0.1 to 700.0 μM), detection limit (65.0 nM), and reproduc...

The voltammetric behaviour of the purine base guanine and the corresponding n,.,c!eoside guanosine at a glaxgy carbon ek~rode was investigated with the help of ultrasound. The adsorption of guanine and guanosiae as well as the adsorption of tJieir ox~Kion pf~:gh~ affects the overall voltammetric characteristics dramatically. In particular, the effect of ultrasound on the simultaneous adsoq~aa o...

There are several U.S. EPA approved methodologies for the determination of arsenic in ground water. Such technologies are lab-based, time intensive and can lead to a large capital cost for multi-sample analysis. In light of the number of sites found to contain arsenic at levels higher than the maximum contaminant level (MCL), on-site screening and monitoring systems are an attractive alternativ...

Purpose: A new sensitive sensor was fabricated for the determination of ivabradine hydrochloride (IH) based on modification with multiwalled carbon nanotubes using sodium dodecyl sulfate as micellar medium to increase the sensitivity. Methods: The electrochemical behavior of IH was studied in Britton-Robinson buffer (pH: 2.0-11.0) using cyclic and differential pulse voltammetry. Results: The vo...

Differential pulse cathodic adsorptive stripping voltammetric method was developed for the determination of prednisolone based on electrochemical reduction of the drug at a hanging mercury drop electrode (HMDE) in 0.04 M Britton-Robinson buffer pH 3.5. The peak current varied linearly over the concentration range 7.21-144.2 ng/ml prednisolone with limit of detection and limit of quantification ...

A simple, accurate and sensitive voltammetric method for determination of Anagrelide (ANG) using β cyclodextrin modified carbon paste electrode (CDMCPE) is developed. CDMCPE exhibited significantly increased sensitivity and selectivity for ANG compared to Carbon paste electrode. Peak currents showed a linear response in the concentration range 1.8 × 10-9 to 1.6 × 10-6 M at CDMCPE. Limit of dete...

A simple and rapid method was developed using cyclic, differential pulse and square wave voltammetric techniques for the determination of trace-level chalcone at a glassy carbon electrode. Chalcone could produce two anodic peaks at about 0.514 V and 1.478 V and a cathodic peak at about −0.689 V. The differential pulse voltammerty presents a good linear response as compared to square wave voltam...

A voltammetric biosensor was developed for the assay of microorganism populations. A tetracycline-modified glassy carbon electrode was used in the construction of the biosensor and an electrochemical cell with an elastic base was employed in the measurement. The possible mechanism of the electrode response was discussed. The determination limit of the microbial populations was 2–5 × 104 cells w...

The electrochemical oxidation behavior and voltammetric assay of gemifloxacin were investigated using differential-pulse and cyclic voltammetry on a screen-printed carbon electrode. The effects of pH, scan rates, and concentration of the drug on the anodic peak current were studied. Voltammograms of gemifloxacin in Tris-HCl buffer (pH 7.0) exhibited a well-defined single oxidation peak. A diffe...