The crystal structure, phonon spectrum, and elastic constants of a series rare-earth germanates (including yttrium germanate R2Ge2O7 (R = Tb-Lu, Y)) with tetragonal structure have been ab initio calculated within the density functional theory. frequencies types fundamental vibrations intensities IR Raman modes are determined. degrees participation ions in each mode determined by analyzing displ...

introduction: ablative and nonablative lasers have been used to treat melasma. we aimed to assess and compare the combining q-switched nd:yag laser (qsnyl) and fractional erbium:yag laser (feyl) with qsnyl alone in treatment of melasma. methods: this randomized controlled clinical trial was performed in our research center during 2013-2014. women with melasma and without a history of keloid for...

The magnetic measurements and resonance studies on pseudobinary cubic compounds suggest that the 3d electrons of transition metal atoms do not share a common 3d band. Although the magnetic properties of pseudobinary rare-earth (yttrium)-transition metal (T) compounds of R@kTT -3,-type have been studied generally [l] we have no information on the individual magnetic behaviour of T' and T atoms. ...

background: radioactive yttrium glass microspheres are used for liver cancer treatment. these yttrium aluminum silicate microspheres are synthesized from yttrium, aluminum and silicone oxides by melting. there are two known processes used to transform irregular shaped glass particles into microspheres, these ‘spheroidization by flame’ and ‘spheroidization by gravitational fall in a tubular furn...

A new hydrated yttrium copper tellurite nitrate, yttrium(III) copper(II) bis-[trioxidotellurate(IV)] nitrate trihydrate, has been synthesized hydro-thermally in a Teflon-lined autoclave and structurally determined using synchrotron radiation. The new phase is the first example containing yttrium, copper and tellurium in one structure. Its crystal structure is unique, with relatively strongly bo...

A laser ion source is under development at the IGISOL facility, Jyväskylä, in order to address deficiencies in the ion guide technique. The key elements of interest are those of a refractory nature, whose isotopes and isomers are widely studied using both laser spectroscopic and high precision mass measurement techniques. Yttrium has been the first element of choice for the new laser ion source...

Solid-state Ln-Bz compounds, where Ln stands for trivalent lanthanides and Bz is benzoate have been synthesized. Simultaneous thermogravimetric and differential thermal analysis in a CO2 atmosphere were used to study the thermal decomposition of these compounds.

A joint experimental/theoretical study has been carried out on the putative MMA polymerization catalyzed by an yttrium isopropyloxide complex. Despite its high activity in lactone polymerization, this catalyst is found to be unreactive on methyl methacrylate (MMA) polymerization. This surprising result is rationalized using a computational approach at the DFT level. Indeed, the endothermicity o...

-Yttria (Y2O3) has become a promising gate oxide material to replace silicon dioxide in metal-oxide-semiconductor (MOS) devices. The characterization of native point defect in Y2O3 is essential to understand the behavior of the material. We used the firstprinciples pseudopotential method to study the electronic structure, defect structure and formation energy of native point defects in Y2O3. Va...

A synthetic avenue for the formation of yttrium oxide thin films on Si native oxide surfaces is demonstrated by the reaction of Tris(2,2,6,6tetramethyl-3,5-heptanedionato) yttrium(III) with inorganic (H2O2) and organic (tert-butyl and di-tert-amyl) peroxides in supercritical carbon dioxide. The reactions are carried out in a hot wall reactor at temperatures below 130 °C and pressures ranging fr...