Thin solid films consisting of ZrO2 and Fe2O3 were grown by atomic layer deposition (ALD) at 400 °C. Metastable phases of ZrO2 were stabilized by Fe2O3 doping. The number of alternating ZrO2 and Fe2O3 deposition cycles were varied in order to achieve films with different cation ratios. The influence of annealing on the composition and structure of the thin films was investigated. Additionally, ...

The band alignment of ZrO2/interfacial layer/Si structure fabricated by simultaneous oxidation and nitridation of sputtered Zr on Si in N2O at 700°C for different durations has been established by using X-ray photoelectron spectroscopy. Valence band offset of ZrO2/Si was found to be 4.75 eV, while the highest corresponding conduction offset of ZrO2/interfacial layer was found to be 3.40 eV; owi...

New MoO3 or WO3 modified CeO2-ZrO2 aerogel catalysts were elaborated using the sol gel method combined to supercritical drying for NO-SCR by NH3 in excess of O2. XRD, N2-Physisorption, NH3-TPD, H2-TPR and DRUV-Vis spectroscopy used analyse samples. The results reveal that all powders (ZrO2, CeO2-ZrO2, MoO3-ZrO2, WO3-ZrO2, MoO3-CeO2-ZrO2 WO3-CeO2-ZrO2), calcined at 500 °C, are nanostructured mes...

Large-scale characterization of phosphoproteins requires highly specific methods for the purification of phosphopeptides because of the low abundance of phosphoproteins and substoichiometry of phosphorylation. A phosphopeptide enrichment method using ZrO2 nanoparticles is presented. The high specificity of this approach was demonstrated by the isolation of phosphopeptides from the digests of mo...

Combinations of three simple techniques were utilized to gradually form zirconia nanoneedles from zirconium nanograins. First, a physical vapor deposition magnetron sputtering technique was used to deposit pure zirconium nanograins on top of a substrate. Second, an anodic oxidation was applied to fabricate zirconia nanotubular arrays. Finally, heat treatment was used at different annealing temp...

ZrO2 nanoparticles were synthesized by a vapor-phase hydrolysis process, and characterized in terms of crystalline structures, hardness and microstructures by X-ray diffraction, Vickers hardness test method, and atomic force microscopy (AFM) measurements. Moreover, in vitro cytotoxicity evaluation and hemolysis assay showed that the nanoparticles possessed good biocompatibility. Hardness invest...

Zirconia (ZrO2) is a well known oxide refractory material, possessing high strength and high melting point. Black zirconia is a variant of conventional zirconia obtained by the addition of a pigments percentage which changes its color from white to black. The present work shows, for the first time to the best of our knowledge, optical spectra of black ZrO2 in the range 0.3-16.3 μm, comparing th...

Rhodium on a La-containing ZrO2 support effectively eliminated NOx from a synthetic auto exhaust gas under fluctuating oxygen conditions. Rhodium particles maintained a low oxidation state on the ZrO2-La2O3 mixed oxide even after treatment with 5% O2 at 773 K, highlighting the significant effect of the La addition.

zro2 nanopowder was prepared by the sol-gel auto-combustion method. the product was characterized by x-ray diffraction (xrd), energy dispersive analysis of x-ray (edx) and scanning electron microscopy (sem). the average crystalline size of zro2 was obtained 62 nm. also, photocatalytic removal of nitrophenol from aqueous solution by using nanoscale zro2 under uv light irradiation was studied. th...

In this study, 10 mol% ZrO2 was added to a 27CaO-5P2O5-68SiO2 (mol%) base composition synthesized via a simple sol-gel method. This composition is similar to that of a frequently investigated bioactive gel-glass. The effects of ZrO2 on the in vitro bioactivity and MG-63 cell proliferation of the glass and its derivative polycrystalline (glass-ceramic) powder were investigated. The samples were ...