The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetra-dentate 2-pyridine-aldazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octa-hedral based on a cis-N(2)S(4) donor set. In the crystal structure, mol-ecules are connected into a supra-molecular chain aligned along the a direction via C-H⋯S and C-H⋯π co...

The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 2,2'-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C-H⋯S inter-actions, leading to linear supra-molecular chains along the a axis. The primary connections betwe...

The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa-hedral N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H⋯S, C-H⋯π(ZnS(2)C) and π-π [ring centroid distance between centrosymmetri...

The complete mol-ecule of the title compound, [Zn(C(4)H(8)NS(2))(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C-C bond of the 2,2'-bipyridine mol-ecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-...

The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa-coordinated by two dithio-carbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl mol-ecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N(2)S(4) donor set. Supra-molecular chains, aligned along the a-axis direction, are mediated by C-H⋯S inter-actions and...