This paper describes a new multilayer TBC that incorporates a 10 μm-thick oxygen barrier layer of yttrium–aluminum garnet (YAG) into a typical YSZ TBC system. The thermal conductivity of as-sprayed YAG/YSZ coatings was reduced due to excessive porosity and amorphous areas in the YAG layer. After long-term heat treatments, the conductivity of the multilayer was unaffected by the presence of YAG....

The combined phase-inversion and sintering method not only produces ceramic hollow fibre membranes with much lower fabrication costs than conventional methods, but these membranes can also be designed to have greatly reduced transport resistances for filtration processes. The bottleneck of this technique is the weak mechanical property of the fibres, due to the small dimensions and the brittle ...

A one-dimensional button-cell model is developed and applied to explore the influence of anode microstructure on solid oxide fuel cell (SOFC) performance. The model couples porous-media gas transport and elementary electrochemical kinetics within a porous Ni-YSZ cermet anode, a dense YSZ electrolyte membrane and a composite LSM-YSZ cathode. In all cases the fuel is humidified H2 and air is the ...

The effect of an 80 nm YSZ interfacial layer, deposited onto a YSZ pellet by different techniques (dip-coating, sputtering and atomic layer deposition) at the SOFC cathode/electrolyte interface to allow a maximum adhesion of the thick cathode layer, was thoroughly analysed. The LSM cathode was deposited on the solid electrolyte by painting and sintered in air at 1200°C for 2 h. The morphologica...

Functionally graded materials (FGM) in the form of layered structure consisting of yttria stabilized zirconia (8 mol% Y2O3) and nickel were fabricated by spark plasma sintering procedure. The relative density, linear shrinkage and Vickers hardness of each layer of graded materials were measured. The microstructure and the composition of these components were studied. The results obtained show t...

Crystalline yttria-stabilized zirconia oxide (YSZ) film was successfully deposited on a silicon wafer without an interfacial amorphous SiO2 layer. The film with equivalent oxide thickness teox down to 1.77 nm shows negligible hysteresis and low interface state density, less than 3 × 1011 cm−2 eV−1. The leakage current density for teox = 1.77 nm film, 1.5 × 10−5 A cm−2 at 1 V bias voltage, is fi...

Half-cell potentials of the electrochemical cell Au, VWT | YSZ | Au are analyzed in dependence on oxygen and ammonia concentration at 550 °C. One of the gold electrodes is covered with a porous SCR catalyst, vanadia-tungstenia-titania (VWT). The cell is utilized as a potentiometric ammonia gas sensor and provides a semi-logarithmic characteristic curve with a high NH3 sensitivity and selectivit...

In this study, small fraction of NiTi (5 wt%) was added to Yttria stabilized zirconia (YSZ) top coat to improve it sliding wear resistance. The measurement of width of wear tracks after wear tests under a 15 N load for 100 m sliding distances showed that the width of wear track in NiTi-YSZ coating is shorter than that in YSZ coating which depicts the higher wear resistance of NiTi-YSZ coa...