نتایج جستجو برای: 1 octene
تعداد نتایج: 2752654 فیلتر نتایج به سال:
The effect of tetrabutylammonium nitrate ([N4444][NO3]) was studied as a surface coating over 1Pd9Ag/Al2O3 and applied in the selective hydrogenation 1,7-octadiene mixture with 1-octene. Weight loadings up to three monolayers (MLs) were investigated further comparison 1-ethylimidazole ([EIM]) carried out assess anionic effects Solid Catalysts an Ionic Liquid Layer (SCILLs). characterised by H2-...
In the title compound, C25H23Cl2N3, the cyclo-octene ring adopts a twist chair-chair conformation. The dihedral angles between the central pyridine ring (r.m.s. deviation = 0.013 Å) and the pendant chloro-benzene and benzyl rings are 78.07 (11) and 87.47 (12)°, respectively. No directional inter-actions could be identified in the crystal and the packing is governed by van der Waals inter-actions.
Four silica samples were evaluated as supports in the hydroformylation of oct-1-ene by Supported Aqueous Phase Catalysis (SAPC) using [Rh2(μ-SBu)2(CO)2(TPPTS)2] and [Rh(COD)Cl]2/TPPTS as catalysts. Adsorption studies of the [Rh(COD)Cl]2/TPPTS complex from aqueous solutions on the supports were carried out at 25 °C. The isotherms obtained were correlated by several models, among which the Fowler...
A new concept for generation of chelating ligand libraries for homogeneous metal complex catalysis based on self-assembly is presented. Thus, self-assembly of structurally simple monodentate ligands in order to give structurally more complex bidentate ligands is achieved employing hydrogen bonding. Based on this concept and on the 2-pyridone/hydroxypyridine tautomeric system, a new rhodium cata...
The oligomerisation of ethylene to linear alpha olefins is an important industrial process for the production of polyethylene co-monomers, plasticizers, surfactants and waxes. With the ever increasing market demand for short chain linear alpha ole fins (1-butene, 1-hexene and 1-octene) there has been intensive research in both industry and academia on methods to selectively oligomerise ethylene...
Silane (Si—H) additions to unsaturated hydrocarbons constitute an important reaction for the formation of the silicon—carbon bond, both from a synthetic1 and industrial viewpoint2. Several catalyst systems have been employed and the literature is replete with reactions catalyzed by peroxideic, chioroplatinic acid and platinized charcoal. Less extensively covered has been the catalysis by organi...
High catalytic activity (turnover frequencies up to 700 h) was achieved using new triphenylphosphinefunctionalized core cross-linked micelles, TPP@CCM, as nanoreactors and [Rh(acac)(CO)2] as catalyst precursor for the aqueous biphasic hydroformylation of 1-octene. While the hydrophobic core of the polymer offers an adequate environment for the catalytic reaction, its hydrophilic shell confines ...
Irritation of the eyes, nose, and throat by airborne chemicals--also referred to as "sensory irritation"--is an important endpoint in both occupational and environmental toxicology. Modeling of human sensory irritation relies on knowledge of the physical chemistry of the compound(s) involved, as well as the exposure parameters (concentration and duration). A reciprocal relationship between thes...
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