N,N-bis(2-quinolinylmethyl)benzylamine (1) was synthesized under basic conditions from a pseudo-three-component reaction between benzylamine and two molecules of 2-(quinolinylmethyl)chloride, resulting in the formation N–C bonds single step. Compound crystallizes triclinic system P-1 space group. The unit cell comprises dimer 1, which monomers are linked by complementary hydrogen N1 H′1–C′1 ano...