The new complexes [M(2)O(5)L(2)(H(2)O)(2)] . H(2)O (M = Mo, 1; M = W, 2), [RuL(2)(H(2)O)(2)] . H(2)O (3), [ML(3)] . xH(2)O (M = Rh, x = 2, 4; M = Ir, x = 1, 5), [RhL(2)(PPh(3))(2)](ClO(4)) . 2H(2)O (6), [PdL(2)] . 2H(2)O (7), [PdL(phen)]Cl . H(2)O (8), [Re OL(2)(PPh(3))]Cl (9) and [UO(2)L(2)] (10) are reported, where LH is 4,6-diamino-1-hydro-5-hydroxy-pyrimidine-2-thione. The complexes were ch...

New pyrimido [4, 5-e] [1, 3, 4]thia- diazin-7-yl] hydrazines were synthesized via the cyclocondensation of alkyl-2-phenylhydrazinecarbodithioates as a binucleophile with 5-bromo-2,4-dichloro-6-methylpyrimidine as a bielectrophile , and replacement of C-7 chloro atom by hydrazine in ethanol as the solvent . This method has advantages over methods currently described in the literature for the con...

The title compound, C(16)H(14)O(5)·2H(2)O [systematic name: 5-hy-droxy-2-(4-hy-droxy-phen-yl)-7-meth-oxy-chroman-4-one dihydrate], is a natural phytoalexin flavone isolated from the native chilean species Heliotropium taltalense and crystallizes with an organic mol-ecule and two water mol-ecules in the asymmetric unit. The 5-hy-droxy group forms a strong intra-molecular hydrogen bond with the c...

1 Aims: Our main objective was to analyze individual determinants that lead middle-2 aged women to seek medical care for UI. 3 Methods: Observational longitudinal study among GAZEL cohort participants: 2640 4 women aged 50-62 completed a self-administered questionnaire at baseline. Eight 5 years later (2008) 2273 (86%) responded to a follow-up questionnaire. Seeking care 6 for UI was defined as...

Abstract The oxidation of various non‐S‐oxidized 4 H ‐1,2,6‐thiadiazines with N 2 O , meta ‐chloroperbenzoic acid ( m ‐CPBA), Oxone, [bis(trifluoroacetoxy)iodo]benzene (PIFA) and phenyliodine (III) diacetate (PIDA) is reported. Six 3,5‐diamino‐4 ‐1,2,6‐thiadiazin‐4‐ones were oxidized to the corresponding sulfones (67–95 % yields) most efficiently using PIFA (3 equiv.). A 3,5‐diphenylthio analog...

The asymetric unit of the title salt, 3CH(5)N(2)S(+)·3Cl(-)·2CH(4)N(2)S, contains two mol-ecules of thio-urea, three (diamino-methyl-idene)sulfonium cations and three chloride anions. The crystal packing is stabilized by N-H⋯Cl, N-H⋯S, S-H⋯Cl and S-H⋯S hydrogen bonds, forming a three-dimensional network.