A homologous series of cationic gas-phase clusters of dicarboxylic acids (oxalic acid, malonic acid, succinic acid, glutaric acid, and adipic acid) generated via electrospray ionization (ESI) are investigated using collision-induced dissociation (CID). Singly charged cationic clusters with the composition (Na(+))(2n+1)(dicarboxylate(2-))(n), where n = 1-5, are observed as major gas-phase specie...

a new mixed  halo chromate  nanoparticle compound was synthesised and characterized. triphenylphosphonium trifluoroiodochromate (iii)[p(c6h5)3h]+[crf3i]- nanoparticle was synthesized by using triphenylphosphonium  iodide reaction with crf3, in the presence of  3-mercaptopropionic acid. this method is a simple and direct method. the product was characterized by spectroscopic and analytical metho...

Lung cancer mortality among 1152 men working at three English chromate pigment factories was studied from the 1930s or 1940s until 1981. Workers at factory C were exposed only to lead chromate and experienced normal mortality (Obs/Exp deaths 7/6.45). Workers at factories A and B were exposed to both lead and zinc chromate; mortality was normal among those who had only low exposure (O/E 7/6.95)....

Equilibrium structures and the respective binding energies of acetic acid monohydrates and dihydrates have been determined by density-functional theory calculations with different basis sets, including 6-31+G(3d,p), 6-311++G(d,p), and 6-311++G(3df,3pd). Given that the C=O and OH groups in acetic acid provide the predominant hydrogen-bonding interactions with water, six stable conformer structur...

Background: Chromium (Cr), a naturally occurring heavy metal, exists in many states, but the trivalent Cr (III) and hexavalent Cr (VI) forms are the most common in the environment. Acute and chronic toxicity in both animal and man are mainly caused by Cr (VI) compounds. Studies on hematological parameters in sub-acute toxicity of potassium chromate in broiler chicks are limited. Aims & Objectiv...

Chromium (VI), also known as hexavalent chromium, is the second most stable oxidation state of chromium. Rarely occurring naturally, most chromium (VI) compounds are manufactured (products or by-products). Chromium (VI) can be reduced to the more stable chromium (III) in the presence of reducing agents (e.g. iron) or oxidizable organic matter (OSHA, 2006). Selected chemical and physical propert...

The hydro-chloride salt of chiral l-nebivolol {systematic name: (+)-(R,S,S,S)-bis-[2-(6-fluoro-3,4-dihydro-2H-1-benzopyran-2-yl)-2-hydroxy-ethyl]ammonium chloride dihydrate}, C(22)H(26)F(2)NO(4) (+)·Cl(-)·2H(2)O, was obtained by chiral liquid chromatography as a dihydrate. The pyran rings adopt half-chair conformations. Hydrogen bonds between the cation, anions and water mol-ecules contribute t...

This proposed research aims to use novel nanoparticle sensors and spectroscopic tools constituting surface-enhanced Raman spectroscopy (SERS) and Fluorescence Lifetime imaging (FLIM) to study intracellular chemical activities within single bioremediating microorganism. The grand challenge is to develop a mechanistic understanding of chromate reduction and localization by the remediating bacteri...

Chromate-induced physiological stress in a water-submerged macrophyte Callitriche cophocarpa Sendtn. (water starwort) was tested at the proteomic level. The oxidative stress status of the plant treated with 1 mM Cr(VI) for 3 days revealed stimulation of peroxidases whereas catalase and superoxide dismutase activities were similar to the control levels. Employing two-dimensional electrophoresis,...