The abatement of particulate matter in gasoline direct injection (GDI) engines requires the use filters. In turn, optimisation their regeneration is based on a deep knowledge soot oxidation behaviour. determination intrinsic kinetic parameters GDI explored thermogravimetric analysis (TGA) and reaction rate modelling. New understanding provided enabling an accurate prediction wide range temperat...

the present article serves the purpose of pursuing geometrization of heat flow on volumetrically isothermal manifold by means of rf approach. in this article, we have analyzed the evolution of heat equation in a 3-dimensional smooth isothermal manifold bearing characteristics of riemannian manifold and fundamental properties of thermodynamic systems. by making use of the notions of various curva...

Isothermal titration calorimetry has been applied in combination with a moisture generator and, independently, gravimetry to study the adsorption of water onto 50 mg of the lipid dioleoylphosphatidylcholine. During the experiment, the relative humidity is varied stepwise, e.g. from 2% to 92% in increments of 2% every 15 min. The difference between the partial molar enthalpy of the water molecul...

Both enantiomers of trans-cyclohexane-1,2-diammonium sulfate and trans-1,2-diphenylethylenediammonium sulfate were used as "tailor-made" additives to direct the mirror-symmetry breaking in the attrition-enhanced deracemization (i.e. Viedma ripening) of conglomerate crystals of ethylenediammonium sulfate (EDS). Isothermal titration calorimetry (ITC) shows chiral recognition of (1R,2R)- and (1S,2...

Ion exchange chromatography is a widely used method for purification of all types biomolecules in current biotechnological downstream processes. Knowledge on the binding behavior proteins provides valuable insight understanding molecular mechanisms protein interactions biological context. However, thermodynamic parameters such as enthalpy and entropy changes that characterize adsorption are sti...

Interactions between the polysaccharide chitosan and negatively charged phospholipid liposomes were studied as a function of compositional and environmental conditions. Using isothermal titration calorimetry, different levels of deprotonation of chitosan in acidic solutions were attained with titration of the fully protonated polymer at pH 4.48 into solutions with increasing pH. The process was...

Material adsorption, the reverse process of evaporation diffusion, directly reflects the wettability of materials. Wettability is one of the main factors that affect the drying shrinkage of materials. A device that measures the wettability of recycled aggregate concrete (RAC) with fly ash is proposed in this study based on pore structure theory. The isothermal absorption curve of RAC is examine...

In this research, nickel ferrite (NiFe2O4) nanoparticles (NFNs) are prepared through coprecipitation method, and applied for adsorption removal of a model organic pollutant, methyl orange (MO). The characterization of t...

The particle size of apatite is one of the critical factors that influence the adsorption of heavy metals on apatite in the remediation of heavy metal contaminated soils using apatite. However, little research has been done evaluating the impact of different particle sizes of apatite on immobilization remediation of heavy metal polluted soils in field. In this study, the adsorption isothermal e...

In situ gas content is an important parameter associating coalbed methane, while the influence of pressure and temperature on methane adsorption desorption still needs to be revealed. this study, molecular structure capacity anthracite coal collected from Diandong Coalfield (China) were studied based 13C nuclear magnetic resonance (13C NMR), Fourier transform infrared spectroscopy (FT-IR), isot...