We present the ReaxFF reactive force field developed to provide a first-principles-based description of oxygen ion transport through yttria-stabilized zirconia (YSZ) solid oxide fuel cell (SOFC) membranes. All parameters for ReaxFF were optimized to reproduce quantum mechanical (QM) calculations on relevant condensed phase and cluster systems. We validated the use of ReaxFF for fuel cell applic...

Hot reformate gas produced by reforming of heavy fuels, such as JP-8, must be desulfurized prior to its use in a solid oxide fuel cell (SOFC). This requires development of sorbent materials with high sulfur absorption efficiency and capacity at the SOFC operating temperature (650-800 C) to avoid heat exchanger penalties. Sorbent performance stability in cyclic operation of sulfidation and regen...

This work concerns robust static output feedback controller (SOFC) design for uncertain and disturbed Takagi-Sugeno (TS) systems using an H-infinity criterion. The main result is based on a descriptor formulation of the closed-loop dynamics. The proposed approach allows avoiding appearance of crossing terms between the controller’s and the TS system’s input matrices leading to easier LMI formul...

A comprehensive mathematical model of the performance of the cathode-supported solid oxide fuel cell (SOFC) with syngas fuel is presented. The model couples the intricate interdependency between the ionic conduction, electronic conduction, gas transport, the electrochemical reaction processes in the functional layers and on the electrode/electrolyte interfaces, methane steam reforming (MSR) and...

In recent years, there has been considerable interest in the potential of quinones as a promising category electroactive species for use aqueous organic redox flow batteries. These materials offer tunable properties and ability to function both positive negative electrolytes, making them highly versatile suitable range applications. Ongoing research focused on improving stability, solubility, p...

Robotic systems are complicated, nonlinear, multiple-input multiple-output (MIMO) systems, which make the design of model-based controllers for robotic systems particularly difficult. Moreover, to achieve reasonable control performance, the dynamic coupling effects between degrees of freedom (DOFs) of the robotic systems must be overcome during the control process. Although a model-free, self-o...

This work aims to analyse and compare the thermodynamic performance size of two types solid oxide fuel cell (SOFC)-based plants. The former is conventional H2-fed plant based on SOFC with an oxygen-ion conducting electrolyte (SOFC-O), latter using a proton-conducting (SOFC-H). Thermodynamic analysis reveals that in SOFC-H system, due H2O formation at cathode side, not only anode concentration l...

One factor limiting solid oxide fuel cell (SOFC) performance is the degradation of chromium containing, ferritic stainless steel, interconnects during operation. When chromium-containing steels are used as interconnect materials a chromium oxide layer forms on the surface. Under SOFC operating conditions (Cathode gas 800oC and 2.5-3.1% H2O) chromium ions are vaporized by the cathode gas and red...

Using learning vector quantization (LVQ) network to construct a self-organizing fuzzy controller (SOFC) for multivariable nonlinear composite systems is developed in this paper. The LVQ network is used to provide information about the better locations of the IF-part membership functions through un-supervised learning. The generated fuzzy rule base is applied to the SOFC and updated by a self-le...

A novel hybrid device exploiting waste heat in solid oxide fuel cells is designed. The hybrid device includes a solid oxide fuel cell and a thermophotovoltaic cell. The performances of the hybrid device and the single SOFC are compared. The optimally operating regions of the hybrid device are determined. The advantages of the hybrid device over other SOFC-based hybrid systems are shown. a r t i...