Carbon film disk electrodes with Nafion coatings have been characterized by electrochemical impedance spectroscopy (EIS) with a view to a better understanding of their advantages and limitations in electroanalysis, particularly in anodic stripping voltammetry of metal ions. After initial examination by cyclic voltammetry, spectra were recorded over the full potential range in acetate buffer sol...

Polyphenol compounds, such as caffeic acid, are important substrates of oxidation in beverages such as wine, and more rapid and sensitive methods of analysis are being sought. The conducting polymer poly-3,4-ethylenedioxythiophene (PEDOT) provides good separation of caffeic acid from antioxidant additives in wines, and produces a clear anodic peak that can be used to quantify caffeic acid and r...

The kinetics of anodic oxidation of zircaloy-2, zircaloy-4, titanium and niobium have been studied in 0.1M sodium methoxide without and with addition of a millimole of sodium phosphate at a constant current density of 8mA.cm-2 and at room temperature (300 K). the addition of phosphate ions found to improve the kinetics of film formation. This trend and mechanism of anodic oxide film growth is c...

in this study, undoped zno and doped with fe and mn nanostructures were synthesized by hydrothermal method. the morphology of nanostructures was characterized by scanning electron microscope. the electrochemical response of the carbon paste electrode modified with nanoparticles of zno and also zno doped with fe and mn toward levodopa (l-dopa) was studied. studies of cyclic voltammetry using pro...

The influence of nanoparticle aggregation on anodic stripping voltammetry is reported. Dopamine-capped silver nanoparticles were chosen as a model system, and melamine was used to induce aggregation in the nanoparticles. Through the anodic stripping of the silver nanoparticles that were aggregated to different extents, it was found that the peak area of the oxidative signal corresponding to the...

Titanium implants have a thin oxide surface layer. The properties of this oxide layer may explain the good biocompatibility of titanium implants. Anodic oxidation results in a thickening of the oxide film, with possible improved biocompatability of anodized implants. The aim of the present study was twofold: (1) firstly, to characterize the growth behaviour of galvanostatically prepared anodic ...

Paper present possibility of creation a neuromatrix in the form crossbar architecture on silicon substrate is shown. Crossbar set nanosized conductors, between which there layer titanium oxide, capable changing its conductivity under action applied voltage, it proposed to using method local anodic oxidation. The results study technological parameters oxidation and for implementation elements th...

Green hydrogen: Cyanide-bound cobalt hydroxides in-situ grown from Prussian blue analogue Co3[Co(CN)6]2 in alkaline solution deliver excellent activity with low anodic onset potential for biomass oxidation. The performance is attributed to the cyanide group and adjacent unsaturated Co sites cooperatively promoting oxidation associated stabilization.