A high content of asphaltene and wax in crude oil leads to difficulties the recovery transportation due precipitation asphaltenes deposition waxes. Comb-like polymers were found be capable inhibiting aggregation crystallization In this work, comb-like bipolymers α-olefins/ultra-long chain (C18, C22 C28) alkyl acrylate synthesized characterized by FT-IR 1H NMR spectra. The results show that, for...

Despite recent advances in spectroscopic techniques, there is uncertainty regarding the nature of the carbonyl groups in the asphaltene and resin fractions of crude oil, information necessary for an understanding of the physical properties and environmental fate of these materials. Carbonyl and hydroxyl group functionalities are not observed in natural abundance 13C nuclear magnetic resonance (...

In the current study, the kinetics of asphaltene particle flocculation is investigated under a shear flow through numerical simulation. The discrete element method (DEM) is coupled with computational fluid dynamics (CFD) to model the agglomeration and fragmentation processes. In addition, a coalescence model is proposed to consider the attachment of colliding particles. The changes in mean asph...

In this study, asphaltene deposition from crude oil has experimentally and theoretically been studied using a test loop and an accurate temperature monitoring during a laminar flow. The effects of oil velocity and surface temperature on the thickness of asphaltene deposition were investigated. The results show that asphaltene deposition thickness increases by increasing surface temperature. As ...

Bridging the gap between laboratory-scale experiments and actual oilfield operations is a complex task that requires compromise real (authentic) fluids model systems. Commercial products (i.e., asphaltene inhibitors dispersants) are often designed to target wide range of operating conditions compositions crude oils, which means performance becomes almost case-specific. Through Atomic Force Micr...

A Ni(II) porphyrin functionalized with an alkyl carboxylic acid (3) has been synthesized to model the chemical behavior of the heaviest portion of petroleum, the asphaltenes. Specifically, porphyrin 3 is used in spectroscopic studies to probe aggregation with a second asphaltene model compound containing basic nitrogen (4), designed to mimic asphaltene behavior. NMR spectroscopy documents self-...