Controlling the corrosion of historical and archaeological ferrous metal objects presents a significant challenge to conservators. Chloride is a major corrosion accelerator in coastal areas for historic ferrous metal structures and for the many chloride-containing archaeological objects within museums. Corrosion reactions involve the formation of akaganéite (βFeOOH) which incorporates chloride ...

Sulfur dioxide (SO2), a typical gaseous compound found in the atmosphere, corrodes metals, particularly outdoors. When SO2 adsorbs on the surface electrolyte, it easily dissolves, resulting in the formation of protons (H+) and bisulfite ions (HSO3). The former reduces the pH of the surface electrolyte, which promotes metal dissolution. Silver and copper are commonly used in the electronic compo...

Reinforcing clamps made of low alloy steel from the Metz cathedral and corroded outdoors during 500 years were studied by OM, FESEM/EDS, and micro-Raman spectroscopy. The corrosion product layer is constituted of a dual structure. The outer layer is mainly constituted of goethite and lepidocrocite embedding exogenous elements such as Ca and P. The inner layer is mainly constituted of ferrihydri...

Corrosion is the process of degradation or failure of a material resulting from a chemical reaction between the material and its surrounding environment. It is an indispensible research area in material science and engineering, because corrosion resistance characterizes the stability or durability of a material, which is one of the most important material performances in application. Compared w...

This thesis presents a new experimental setup for surface analysis studies, incorporating chemical information from infrared reflection absorption spectroscopy (IRAS) and quantitative information from quartz crystal microbalance (QCM). The integrated IRAS/QCM surface analysis system enables in situ studies to be conducted of the metal/atmosphere interaction on a sub-monolayer level. In combinat...