Polystyrene-capped barium titanate (BaTiO3) nanoparticles with sizes of 11 nm and 27 nm were prepared using amphiphilic star-like diblock copolymer templates. The crystal structure evolution of these nanoparticles over a wide temperature range (10-428 K) was investigated by powder X-ray diffraction. The Rietveld refinement indicates that the abrupt structural transitions observed in micron-size...

Perovskite barium titanate (BaTiO3) has received a lot of interest due to its extraordinary dielectric and ferroelectric properties, along with moderate biocompatibility. Here, we investigated how Zn doping tuned the physicochemical characteristics, photocatalytic activity, anticancer potential BaTiO3 nanoparticles synthesized from banana peel extract. XRD, TEM, SEM, EDS, XPS, BET, Raman, PL we...

Flexible, light weight and low cost electroactive coating has been fabricated by the dispersion of inorganic ferroelectric submicron particles in a polyurethane matrix. BaTiO3 particles have a mean diameter of 300 nm. The poling process and the influence of volume fraction of BaTiO3 on the piezoelectric activity of the coating have been reported. This spray coating has been realized on 1.6× 1.6...

We report conduction measurements on the clean, free surface of transparent insulating BaTiO3 single crystals in high vacuum. We find that the insulating BaTiO3 crystals exhibit surface conductance that is dependent on the spontaneous polarization, whereas no conduction perpendicular to the surface is observed. The surface conduction shows semimetallic temperature dependence and persists down t...

This paper presents an enhanced piezoelectricity based sensor for touch and temperature sensing. The sensor is realized over flexible polyimide film, making it suitable for application like e-skin. The sensing material is composed of Polyvinylidene Fluoride-Trifluoroethylene (PVDF-TrFE) and Barium Titanate (BaTiO3) nanoparticles. While, the piezoelectric polymer PVDF-TrFE ensures the flexibilit...

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Using path-integral Monte Carlo simulations and an ab initio effective Hamiltonian, we study the effects of quantum fluctuations on structural phase transitions in the cubic perovskite compounds SrTiO3 and BaTiO3 . We find quantum fluctuations affect ferroelectric ~FE! transitions more strongly than antiferrodistortive ~AFD! ones, even though the effective mass of a single FE local mode is larg...

We have developed a simple, cost-effective, and scalable approach to fabricate a piezoelectric nanogenerator (NG) with stretchable and flexible characteristics using BaTiO3 nanotubes, which were synthesized by the hydrothermal method. The NG was fabricated by making a composite of the nanotubes with polymer poly(dimethylsiloxane) (PDMS). The peak open-circuit voltage and short-circuit current o...

Composite polymer electrolyte (CPE) membranes, comprising poly (vinylidene fluoride) (PVdF)/poly (methyl methacrylate) (PMMA), BaTiO3 as ceramic filler and LiBF4 as the lithium salt were prepared using a solution casting technique. The prepared membranes were subjected to XRD, FT-IR, impedance spectroscopy and thermal stability studies. The incorporation of nanofiller greatly enhanced the ionic...

We report electron paramagnetic resonance measurements on BaTiO3, containing a dilute impurity of Fe , in its ferroelectric phase over a range of pressure and temperature near the paraelectric-ferroelectric phase transition line. We have developed an algorithm to analyze the data, allowing us to determine the values of the crystal field parameters and their temperature and pressure dependence r...