The effect of tin content in the equilibrium phases of the Cu–Zn-based alloys, within the range of chemical compositions with interest to brass producers is described. For this purpose, ternary alloys with copper contents between 55.4 and 67.5 wt.% and tin contents up to 5.30 wt.% have been studied. The chemical composition of each alloy has been determined by X-ray fluorescence spectrometry (X...

Widely known Gibbs' relationship predicting a difference of chemical potentials in a small solid particle and in a surrounding fluid phase at equilibrium is shown to refer to a real or imaginary bulk phase inside the particle. A similar relationship derived for the real surface monolayer of a nanoparticle exhibits the equality of chemical potentials at equilibrium, which allows for experimental...

In this paper, we discuss the dynamical properties of a chemical reactor model including Lyapunov exponents, bifurcation, stability of equilibrium and chaotic attractors as well as necessary conditions for this system to generate chaos. We study the synchronization of chemical reactors model via sliding mode control scheme. The stability of proposed method is proved by Barbalate’s lemma. Numeri...

Chemical and other species reaction theories involving thermodynamical equilibrium states characterized by a temperature parameter invariably utilize statistical mechanical equilibrium density distributions. Here, a definition of heat-work transformation termed thermo mechanical coherence is first made, and it is conjectured that most molecular bonds have the above heat-work transformation prop...

Within the Closed Time Path Formalism of Thermal Field Theory we calculate the hard photon emission rate as well as the collisional energy-loss rate for a quark-gluon plasma away from chemical equilibrium. Mass singularities are shown to be dynamically screened within HTL-resummed perturbation theory also away from equilibrium. Additional (pinch) singularities are absent and well defined result...

Three fast and reversible electrode reactions that are connected by two reversible chemical reactions that are permanently in the equilibrium are analysed theoretically for square wave voltammetry. The dependence of peak potentials on the dimensionless equilibrium constants of chemical reactions is calculated. The influence of the basic thermodynamic parameters on the square wave voltammetric r...