نتایج جستجو برای: chiral

تعداد نتایج: 37423  

2005
R. J. Baxter

The chiral Potts model continues to pose particular challenges in statistical mechanics: it is “exactly solvable” in the sense that it satisfies the Yang-Baxter relation, but actually obtaining the solution is not easy. Its free energy was calculated in 1988 and the order parameter was conjectured in full generality a year later. However, a derivation of that conjecture had to wait until 2005. ...

1992
Srinandan Dasmahapatra Rinat Kedem Barry M. McCoy

We find the rules which count the energy levels of the 3 state superintegrable chiral Potts model and demonstrate that these rules are complete. We then derive the complete spectrum of excitations in the thermodynamic limit in the massive phase and demonstrate the existence of excitations which do not have a quasi-particle form. The physics of these excitations is compared with the BCS supercon...

1999
H. H. Perk

In this paper we study the large-N limits of the integrable N-state chiral Potts model. Three chiral solutions of the star-triangle equations are derived, with states taken from all integers, or from a finite or infinite real interval. These solutions are expected to be chiral-field lattice deformations of parafermionic conformal field theories. A new two-sided hypergeometric identity is derive...

2016
Hai-Long Qian Cheng-Xiong Yang Xiu-Ping Yan

Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach ...

2015
Joshua D. Horvath Andrew J. Gellman

Chiral surfaces are of growing importance as a result of their potential for use in enantioselective chemical processes. By far the most widely used and commonly studied chiral surfaces are those prepared by templating of achiral surface with chiral organic ligands. It is possible, however, to prepare naturally chiral surfaces by a number of means. This paper describes the various types of chir...

Journal: :ACS nano 2010
Andrew J Gellman

Chiral surfaces serve as media for enantioselective chemical processes. Their chirality is dictated by atomic- and molecular-level structure, and their enantioselectivity is determined by their enantiospecific interactions with chiral adsorbates. This Perspective describes three types of chiral metal surfaces: those modified by adsorption of chiral molecules, those templated by chiral lattices ...

2015
Gonçalo José da Silva Pimenta

The focal purpose of this thesis is to study chirality specifically in telecommunications area, through the pure chiral fibres (optical fibres constituted by chiral material) and chiral fibre grating (twisted optical fibre), analysing also its behaviour and applications. Nevertheless we shall also address this theme from an economical perspective. The study begins by giving a brief introduction...

Journal: :research in pharmaceutical sciences 0
f hassanzadeh m rahmani khajouei g h hakimelahi e jafari g a khodarahmi

quinazolinones are interesting materials because of their valuable biological effects. in this study some new 2,3-disubstituted-4(3h)quinqzolinone derivatives were synthesized from anthranilic acid in six steps by introducing a new chiral center to the aliphatic side chain of the quinazolinone. in the last step, a single acylation on the hydrazine moiety afforded final compounds. the structures...

Journal: :The Journal of organic chemistry 2008
Shaofang Yu Sergey Lindeman Chieu D Tran

We have synthesized a series of structurally novel chiral ionic liquids which have a either chiral cation, chiral anion, or both. Cations are an imidazolium group, while anions are based on a borate ion with spiral structure and chiral substituents. Both (or all) stereoisomeric forms of each compound in the series can be readily synthesized in optically pure form by a simple one-step process fr...

2007
Michael Flohr

Although logarithmic conformal field theories (LCFTs) are known not to factorise many previous findings have only been formulated on their chiral halves. Making only mild and rather general assumptions on the structure of an chiral LCFT we deduce statements about its local non-chiral equivalent. Two methods are presented how to construct local representations as subrepresentations of the tensor...

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