Ni nanoparticles supported on ZrO2 are a prototypical system for reforming catalysis converting methane to synthesis gas. Herein, we examine this catalyst on a fundamental level using a 2-fold approach employing industrial-grade catalysts as well as surface science based model catalysts. In both cases we examine the atomic (HRTEM/XRD/LEED) and electronic (XPS) structure, as well as the adsorpti...

The unsupported NiBa catalyst has been used in the CO2-SR (CO2 Storage and situ Regeneration with CH4) cyclic technology, which allows use of CO2 from combustion CH4 biogas order to produce enriched syngas streams. isotopic study transient regime, using 13CO2 CD4 instead 12CO2 CH4, respectively, performed discriminate different carbon hydrogen sources participation pathways involved whole proce...

b Catalytic steam reforming of methane, methanol, and ethanol over Ni/YSZ: The possible use of these fuels in internal reforming SOFC N. Laosiripojana a,∗, S. Assabumrungrat b a The Joint Graduate School of Energy and Environment, King Mongkut’s University of Technology Thonburi, Bangkok 10140, Thailand b Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemic...

Pseudomorphism is known as a suitable technique for producing mesoscale pore in silica powders keeping their original morphologies. Herein, silica discs with several millimeter dimensions have been prepared using the same method. This method has been utilized through application of pseudomorphism reaction of preshaped bodies by immersion in a solution containing surfactant and swelling re...

Photocatalytic reduction of CO2 with CH4 through the dry reforming methane (DRM) is an attractive approach to recycling greenhouse gases into valuable chemicals and fuels; however, this process quite challenging. Although there growing interest in designing efficient photocatalysts, they are less stable, have lower photoactivity when employed for DRM reactions. Herein, we developed a noble meta...

An alumina-supported nickel catalyst has been used to effect the ‘dry’ reforming of methane, using CO2 as the oxidant. After 6 hours on-stream, reaction was stopped and the sample analysed by inelastic neutron scattering (INS). The INS spectrum reveals the presence of hydrocarbonaceous species as well as hydroxyl species present at the catalyst surface. Through the use of appropriate reference ...

Ni-YSZ anode supported solid oxide fuel cells (ASCs) were tested under various simulated syngas. There was no voltage degradation of the cell operated on 41%H2-7%CH4-6%CO-11%CO2-35%H2O fuel condition for nearly 450 hours. However, the high vapor content reduced the open circuit voltage (OCV) and discharge voltage. The cells run steadily with most dry syngas until the simulated reforming tempera...

Previous experimental studies have shown that addition of small amounts of oxygen to a hydrocarbon fuel stream can control coking in the anode, while relatively large amounts of oxygen are present in the fuel stream in single-chamber solid oxide fuel cells SOFCs . In order to rationally design an anode for such use, it is important to understand the coupled catalytic oxidation/ reforming chemis...

in this study, a novel solid dendrimer amine (hyperbranched polymers) was prepared using mesoporous carbon nitride functionalized by melamine based dendrimer amines. this adsorbent was denoted mda-mcn-1. the process was stepwise synthesis and hard-templating method using mesoporous silica sba-15 as a template. cyanuric chloride and n,n-diisopropylethylamine (dipea, merck) were used for function...

Elevated concentrations of atmospheric CO2 ([CO2]) enhance the production and emission of methane in paddy fields. In the present study, the effects of elevated [CO2], elevated temperature (ET), and no nitrogen fertilization (LN) on methanogenic archaeal and methane-oxidizing bacterial community structures in a free-air CO2 enrichment (FACE) experimental paddy field were investigated by PCR-DGG...