In this study, large eddy simulations, coupled a two-equation soot model, are performed to investigate the effects of ambient carbon dioxide (CO2) and water (H2O) additions on formation oxidation processes in an n-dodecane spray flame. acetylene (C2H2) is precursor surface growth species, while hydroxyl radical (OH) oxygen (O2) oxidizers. The effect CO2 H2O formation/oxidation can be separated ...

The ternary system H2O-NaCl-CO2 is one of the most important fluid systems in geochemistry and petrology. However, there is little information on the phase equilibrium and PVT properties in this system at salinities above 6 wt.% NaCl. In this study, PVTX data were obtained experimentally by using the synthetic fluid inclusion technique in conjunction with conventional microthermometry and a hyd...

Laboratory spectra have shown that CO2 is a powerful diagnostic tool for analyzing infrared data from remote observations, as it has been detected on icy moons in the outer Solar System as well as dust grain surfaces in the interstellar medium (ISM). IR absorption band profiles of CO2 within ice mixtures containing H2O and CH3OH change with respect to temperature and mixture ratios. In this par...

We present ISO SWS (AOT6) observations of the protostellar object RAFGL 7009S. This source is particularly interesting for the characterisation of chemistry arising from grain surfaces andmantles, since the solid state features ofmany simple molecules such asH2O,CO,CO2, CO2 andCH4 are detected, together with weaker features not yet unambiguously identified. Gas phase H2O, CO2, CH4 and CO can al...

Owing to advances in microanalytical techniques over the last 15 years, there is a growing database on the volatile contents of subduction-related magmas as recorded in melt (glass) inclusions trapped in phenocrysts in volcanic rocks. Basaltic magmas from subduction zones show a wide range of water contents, ranging from as high as 6–8 to b0.5 wt.% H2O. Variations are related in some places to ...

Carbonic acid (H2CO3) forms in small amounts when CO2 dissolves in H2O, yet decomposes rapidly under ambient conditions of temperature and pressure. Despite its fleeting existence, H2CO3 plays an important role in the global carbon cycle and in biological carbonate-containing systems. The short lifetime in water and presumed low concentration under all terrestrial conditions has stifled study o...

The absorption properties of the water vapor continuum and a number of weak bands for H2O, O2, CO2, CO, N2O, CH4, and O3 in the solar spectrum are incorporated into the Fu-Liou radiation parameterization program by using the correlated k-distribution method (CKD) for the sorting of absorption lines. The overlap absorption of the H2O lines and the H2O continuum (2500–14500 cm −1) are treated by ...