in the crystal structure of the title polymeric compound, [c42h38n6o33sr5.2(h2o)]n, five independent metal atoms (sr1-sr5) have different coordination environments. the sr1 and sr5 atoms are nine coordinated and feature distorted tricapped trigonal-prismatic and capped square-antiprismatic geometries, respectively. the rest srii atoms have eight coordination numbers. these units are connected v...

In the present study, a modified Structure Function was introduced. In this modified Structure Function model, the coefficient of model was computed dynamically base on the coherent structure in the flow field. The ability of this Modified Structure Function was investigated for complex flow over a square cylinder in free stream and a low aspect ratio cylinder confined in a channel. The Results...

The first crystal structure of a phenylcyanamide cobaltoxime (cobaloxime) complex is reported. This compound is trans-[Co((DO)(DOH)pn)(2,5-Cl2pcyd)2], and consits of an imine-oxime equatorial ligand ((DO)(DOH)pn) and two 2,5-dichlorophenylcyanamide ligands in axial positions. Crystals of trans- [Co((DO)(DOH)pn)(2,5-Cl2pcyd)2] were grown by ether diffusion into an acetonitrile solution of the co...

A complex of N, N, N', N', -tetramethylated ethylenediamine, TMEDA, with CuCI is prepared. The crystal and molecular structure of this complex is characterized by a single-crystal X-ray diffraction study. The complex is found to contain [Cu (TMEDA) ] cation which is nearly tetrahedral and the [CuCI ) anion is linear which Cu lies on a center of symmetry. Crystals are monoclinic space grou...

in protein biochemistry, biochemists specially study proteins as complex polymers. protein biochemistry is the study of the chemical structure of proteins, including individual amino acids, their linkage as well as physical structure of proteins. proteins, especially globular proteins, are three dimensional in nature. proper function of globular proteins is tightly related to their three-dimens...

this paper investigates the nature of absolutive case and the syntactic mechanisms underlying its licensing. to this end, two recent minimalist approaches to the syntactic derivation of ergative structure will be introduced. drawing on evidence from the syntactic derivation of clauses with intransitive complex predicates in kurdish, it will be established that the absolutive case is checked by ...

the molecular geometry of complex of adenine with 8 water molecules was calculated with hartree-fock (hf). the standard 6-31g(d) basis set has been employed. the existence of c-h…o hydrogen bonds between the water molecules and the hydrophobic part of nucleobase is stablished. we optimized structures and computed interaction energies of all complexes of adenine with water molecules step by step...