abstractinteraction of ni complex(salen= n, n´-ethylene bis(salicylideneimine)) with hen egg-white lysozyme (hewl) was studied by absorption spectroscopy, competitive binding study and thermal denaturation study. the protein binding affinity of ni complex was found to be (3.0×103m−1). the binding plot obtained from the absorption titration data gives a binding constant of 2.4 (± 0.3)×103 m-1. i...

An analytical equation of state was applied to calculate the thermodynamic properties for argon.The equation of state is that of Song and Mason. It is based on a statistical-mechanical perturbationtheory of the hard convex bodies and can be written as fifth-order polynomial in the density. Thereexist three temperature-dependent parameters: the second virial coefficient, an effective molecularvo...

This paper presents the results of an on-going project to develop ThermoCycle, an open Modelica library for the simulation of low-capacity thermodynamic cycles and thermal systems. Special attention is paid to robustness and simulation speed since dynamic simulations are often limited by numerical constraints and failures, either during initialization or during integration. Furthermore, the use...

In this work we obtained a polymer-metal complex by mixing aqueous solution of copper(II) acetate with PVA at certain ratio, pH the and temperature. The composition compound was determined potentiometric conductometric titration. possibility formation proved calculating thermodynamic characteristics. stability constant calculated on basis modified Bjerrum’s method. metal-polymer synthesized in ...

The real-world systems: technological, biological or social networks are networks where connections between elements change in time. In the following we consider how changes in network connections influence properties of the system of ferromagnetically interacting elements living on the evolving network. In particular we concentrate on critical phenomena properties related to both topological c...

Nanostructured amorphous films exhibit complex thermodynamic and kinetic behavior. To understand the structure and properties of nanostructured amorphous films in silicon based ceramics (Si3N4, SiC, Si) and in SrTiO3 ceramics, we have focused on experimental studies to determine the interband electronic structure and optical properties. We use vacuum ultraviolet spectroscopy for bulk materials,...

In this study, the substituent effect on the electronic, spectroscopic properties and thermodynamic parameters of neutral and oxidized states of ferrocylidene acetophenone complexes was investigated by adopting the hybrid meta exchange-correlation functional of M06-2X. The frontier orbitals and the highest occupied molecular orbitals–lowest unoccupied molecular orbitals gaps of the substituted ...