Ammonium tetrathiomolybdate (TTM) is the treatment of choice for chronic Cu poisoning in sheep and is recommended in Wilson's disease. However, the long-term effects have not been fully evaluated and some evidence questions the long-term safety of the drug. The aim of the present study was to investigate the systemic distribution and retention of Cu and Mo in TTM-treated sheep of different bree...

In this study, water samples were collected from 10 thermal and non-thermal springs of Mahalat setting during four periods in 2011. The discharge rates of these springs vary from 2 l/s to 45 l/s and their temperature range from an average minimum of 18oC to maximum 47oC. Spring water is high in SO4-Cl and this is related to gypsum dissolution. Correlation coefficient, principal component analys...

The rumen is the site of significant interactions between Cu, S and Mo. It also shows reactions between Cu, S and Fe. The interaction between Mo and S results in the formation of thiomolybdates, which in the absence of adequate quantities of rumen Cu are absorbed into the animal and bind to Cu in biological compounds. This is the cause of thiomolybdate toxicity, often misleadingly called Cu def...

Under some conditions, the use of high-sulphur fertilisers has been thought to be associated with an increase in the incidence of copper deficiency among ruminants grazing the fertilised pastures or fed treated herbage. In this study 35 Romney lambs grazing ryegrass–white clover pasture of low molybdenum content (<0.5 mg Mo/kg DM) received dietary supplements of elemental S and Cu 3 times weekl...

With the growing availability and use of copper-based nanomaterials (Cu-NMs), there is increasing concern regarding their release and potential impact on the environment. In this study, the short-term (≤5 d) aging profile and the long-term (135 d) speciation of dissolved Cu, copper oxide, and copper sulfide nanoparticles (CuO-NPs and CuS-NPs) were investigated in five different soils using X-ra...

sediments are generally regarded as the sink for dissolved elements carried out to the sea by rivers. in order to study the source and mechanism of metal transport in sea water, 123 surface sediment samples were taken by using grab sampler in the northwest part of the persian gulf in summer. grain size analysis and geochemical analysis by icp-oes were carried out on samples after sample prepara...

In this research, the uptake of Cu, Mo, Zn, As(III) and Cr(VI) by mesquite (Prosopis spp.) roots and shoots from two different sources was studied. The first source was seeds collected from plants grown in mine tailings in Arizona, USA (Seeds A) and the other source was seeds from a commercial vendor (Seeds B). In addition, the effects of above mentioned elements on plant growth and nutrient up...

In this study, inductive coupled plasma-optical emission spectroscopy (ICP-OES) is employed for the evaluation of soil pollution for selected metals in the Vanderbijlpark area of South Africa. Soil samples investigated were collected from five different sites in the city based on their proximity to the industrial areas of Vanderbijlpark. Soil samples were collected from close to traffic robots,...

Molybdenum supported thin films of ScN, MgO and NaF with a Cu adatom have been studied in the framework of density functional theory. We have observed a charge transfer from the metal/film interface to the Cu atom and investigated its relation to surface and interface deformations. We find that a weak interaction between the metal and the film is a promising prerequisite for adatom charging. Th...

A new coordination polymer of polyoxomolybdate, {[Cu(4)(bbp)(5)Mo(6)O(22)]·(H(2)O)(4)}(∞) (bbp = 1,4-bis(benzoimidazol-1-yl)phenyl), has been synthesized under solvothermal reaction, which represents a double-bridging interpenetrating α-Po network based on the bimetallic cluster {Cu(4)Mo(6)}. The thermogravimetric and electrochemical behaviors have also been studied.