A new class of salicylaldiminato tin(II) catalysts having different alkoxy side chains has been developed. The ligands were modified to have different lengths and flexibilities such as –(CH2)2– (2a), –(CH2)3– (2b), –(ortho-C6H4)CH2– (2c) and –(CH2)2–O–(CH2)2– (2d). Complexes 2a, b were characterized crystallographically revealing a more constrained environment around the metal in complex 2a. Th...

We give a construction of Connes-Moscovici’s cyclic cohomology for any Hopf algebra equipped with a character. Furthermore, we introduce a non-commutative Weil complex, which connects the work of Gelfand and Smirnov with cyclic cohomology. We show how the Weil complex arises naturally when looking at Hopf algebra actions and invariant higher traces, to give a non-commutative version of the usua...

The study of protein-protein interactions can be hampered by the instability of one or more of the protein complex components. In this study, we showed that intein-mediated cyclization can be used to engineer an artificial intramolecular cyclic protein complex between two interacting proteins: the largely unstable LIM-only protein 4 (LMO4) and an unstructured domain of LIM domain binding protei...

in this study, a researching program is conducted by cyclic triaxial test to determine the post-cyclic behavior of bushehr carbonate sand retrieved from the north of the persian gulf, under anisotropic consolidation at 200 kpa confining pressure. the article compares the post-cyclic monotonic strength and excess pore water pressures generated after the test with the pre-cyclic monotonic results...

We give an explicit formula for sp2n-basic representatives of the cyclic cohomology of the Weyl algebra HC(A2n). This paper can be seen as cyclic addendum to the paper [6] by Feigin, Felder and Shoikhet, where the analogous Hochschild case was treated. As an application, we prove a generalization of a Theorem of Nest and Tsygan concerning the relation of the Todd class and the cyclic cohomology...

Optimal transcription of the lac operon in a defined purified in vitro system is dependent upon the concentrations of cyclic adenosine 3’,5’-monophosphate (cyclic AMP), the cyclic AMP-binding protein (CRP) and RNA polymerase. The concentration of CRP required for maximal Zac transcription varies proportionately with the concentration of lac DNA used as template. Maximal Zac transcription is obt...

The conformation and ion-binding characteristics of a cyclic octapeptide, cyclo (Ala-Leu-Pro-Gly)2, in a liphophilic solvent, acetonitrile, have been studied using CD and nmr spectroscopy. The peptide binds preferentially to divalent cations such as calcium, magnesium, and barium. The conformations of the free cyclic peptide and its calcium complex are very similar with well-defined beta- and g...

abstract: this paper presents the results of pullout tests on uniaxial geogrid embedded in silica sand under monotonic and cyclic pullout forces. the new testing device as a recently developed automated pullout test device for soil-geogrid strength and deformation behavior investigation is capable of applying load/displacement controlled monotonic/cyclic forces at different rates/frequencies an...

Two fluorine-containing analogues of the cyclic AMP receptor protein (CRP) from Escherichia coli were prepared by biosynthetic incorporation of 5-fluorotryptophan (5-F-Trp) and 3-fluorotyrosine (3-F-Tyr). The 19F-n.m.r. spectrum of the [5-F-Trp]CRP showed two signals corresponding to the two tryptophan residues, and that of the [3-F-Tyr]CRP showed six signals (two overlapping) corresponding to ...

A cyclic molecule including a hexameric PNA sequence has been designed and synthesized in order to target the TAR RNA loop of HIV-1 through the formation of a "kissing complex". For comparison, its linear analogue has also been investigated. The synthesis of the cyclic and linear PNA has been accomplished following a liquid-phase strategy using mixed PNA and fully N-protected (aminoethylglycina...