Pre-shaped mesoporous amorphous rice husk ash (RHA) and MCM-41 derived from RHA as a silica source were transformed into MFI-type zeolites using two different structure-directing agents. Tetrapropylammonium hydroxide (TPAOH) was utilized as an alkali source for silica dissolution and structure control during the direct transformation of RHA into zeolite. A monopropylamine (PA)-containing alkali...

HIGHLIGHTS Fe incorporation significantly accelerated the adsorption of CPX on MCM-41.Fe leaching can be ignored when pH was higher than 4.0.pH played an important role in CPX adsorption on Fe-MCM-41.Co-effect of CPX and metal cations on Fe-MCM-41 was investigated. Fe-MCM-41s with various molar ratios of silicon to iron (20, 40, 80, and 160) were prepared to investigate adsorption properties of...

Biomethane, produced by biogas upgrading, is a promising energy source that can play key role towards net-zero emissions targets. The incorporation of amine functionalities into adsorbents for upgrading facilitate the selective adsorption CO2, but their effect has not been comprehensively studied within context CH4 mixtures. In this work, effectiveness in selectively separating CO2 from biogas,...

MCM-41 and Zn-MCM-41 were successfully synthesized using hydrothermal impregnation methods. The silica mesoporous was confirmed by characterizing the material XRD, SEM-EDS, BET-BJH analyses. XRD results showed three main peaks at angles of 2θ = 2.40° (100), 3.87° (200), 4.49° (210), which are characteristics materials with hexagonal structures. SEM analysis that surface morphology Zn-modified f...

Tetracycline (TC) is a well-known broad spectrum antibiotic, which is effective against many Gram positive and Gram negative bacteria. Controlled release nanoparticle formulations of TC have been reported, and could be beneficial for application in the treatment of periodontitis and dental bone infections. Furthermore, TC-controlled transcriptional regulation systems (Tet-on and Tet-off) are us...

Recently, hybrid materials using poly ethylene glycol and porous nanocrystals have been developed for drug release. In this study, a series of poly ethylene glycol (PEG)/NaY zeolite and PEG/MCM-41 nanocomposites get synthesized. These materials are characterized using FT-IR spectroscopy, XRD, TGA and SEM. After loading the metronidazole onto these nanocomposites, the release of Metronidazole wa...

In this research, the fabrication of MCM-41 mesoporous material nanofibers by an electrospinning technique was performed. The MCM-41 nanofibers (MCM-41 NFs) as a novel host on the incorporation of silver has been studied in [Ag(NH3)2]NO3 precursor solution through the heat-treatment process. The formation of silve...

A new method has been used to obtain pore size characteristics of MCM-41 catalyst supports and vanadiumsubstituted MCM-41 catalysts. The approach is based on the nonlocal density functional theory (NLDFT) model for nitrogen and argon adsorption in MCM-41, proposed recently. Samples with pore sizes varying from ca. 25 to 37 Å were prepared by hydrothermal synthesis. Two synthesis procedures empl...