In this study, a novel least square support vector machine (LSSVM) model integrated with gradient-based optimizer (GBO) algorithm is introduced for the assessment of water quality (WQ) parameters. For purpose, three stations, including Ahvaz, Armand, and Gotvand in Karun river basin, have been selected to electrical conductivity (EC) total dissolved solids (TDS). First, prove superiority LSSVM-...

The objective of this study was to test the hypothesis that serotonin O-sulphate (5-HT-SO4) could be quantified in human plasma using modern liquid chromatography-mass spectrometry (LC-MS) method as well as develop and validate that method. First, a suitable LC-MS method for detection of 5-HT-SO4 in human plasma samples was developed and validated. Second, a Pilot phase involving four healthy v...

The vegetation of Eshtehard salt marshes in Karaj was studied, using the Braun-Blanquet method. Sixty five relevés recorded in different salt habitats were analyzed by Analyse Factorielle des Correspondances (AFC) and Classification Ascendant Hierarchique (CAH) methods, using the Anaphyto software. In general, 11 plant associations determined in the area: Aeluropodetum littoralis, Artemisietum ...

Dermatan sulfate increases the rate of inhibition of thrombin by heparin cofactor II (HCII) approximately 1000-fold by providing a catalytic template to which both the inhibitor and the protease bind. Dermatan sulfate is a linear polymer of D-glucuronic acid (GlcA) or L-iduronic acid (IdoA) alternating with N-acetyl-D-galactosamine (GalNAc) residues. Heterogeneity in dermatan sulfate results fr...

Two novel coordination polymers [Ag16(SO4)8][Ag4(SO4)2]3(L1)12·nH2O (n = 72) (1) and [Ag10(SO4)5(L2)4(H2O)2]·8H2O (2) based on conformationally variable oligo-α-heteroarylsulfanyl ligands 2-(pyrazin-2-ylthio)-6-(pyridin-2-ylthio)pyrazine (L1) or 2,6-bis(pyrazin-2-ylthio)pyrazine (L2) and sulfate-templated high-nuclearity Ag(I) clusters as structure-building units (SBUs) have been synthesized un...

Despite its ubiquity in nature, SO4 22 as an isolated dianion has never been detected because of its electronic instability as a result of the two negative charges. This study shows how the first few waters solvate and stabilize an isolated SO4 , molecule-by-molecule, using photodetachment spectroscopy and theoretical calculations. We find that the minimum number of water required to stabilize ...

A Zr-based MOF, NU-1000, comprised of Zr6 nodes and tetratopic pyrene-containing linkers is studied for adsorption and extraction of SO4(2-) from water. The adsorption capacity and uptake time of SO4(2-) in NU-1000 is determined at varying concentrations to give an overall maximum adsorption capacity of 56 mg SO4(2-) per g of MOF. Selective adsorption of SO4(2-) by NU-1000 in the presence of ot...

16 17 This study characterizes the spatial and temporal patterns of aerosol and precipitation 18 composition at six sites across the United States Southwest between 1995 and 2010. Precipitation 19 accumulation occurs mostly during the wintertime (December February) and during the 20 monsoon season (July September). Rain and snow pH levels are usually between 5 – 6, with 21 crustal-derived speci...