نتایج جستجو برای: fluoro β diketones

تعداد نتایج: 185255  

Journal: :Journal of agricultural and food chemistry 2012
Pepijn Prinsen Ana Gutiérrez José C del Río

The composition of lipophilic extractives in the cortex and pith of elephant grass ( Pennisetum purpureum Schumach.) stems was thoroughly studied by gas chromatography-mass spectrometry. The predominant compounds were fatty acids followed by sterols (in free and conjugated forms as esters and glycosides). Other steroid compounds, as steroid hydrocarbons and ketones, were also present. Addition...

Journal: :Chemical communications 2015
Takashi Matsuno Yutaro Koyama Satoru Hiroto Jatish Kumar Tsuyoshi Kawai Hiroshi Shinokubo

Oxidation of 2-hydroxy-9,10-dialkynylanthracenes resulted in highly regioselective dimerization to furnish metastable dearomatized 1,4-diketones rather than stable aromatic diols. The 1,4-diketones were converted to oxahelicenes, which exhibited strong fluorescence both in solution and solid state as well as chiroptical properties.

Journal: :Chemical communications 2014
Ken Takaki Akira Ohno Makoto Hino Takashi Shitaoka Kimihiro Komeyama Hiroto Yoshida

Thiazolium carbene-catalyzed reaction of aromatic 1,2-diketones with enones in aprotic solvents gave double acylation products in good yields, whereas hydroacylation products formed by Stetter reaction were not detected at all. These results suggested the generation of aroyloxyenamine species from the 1,2-diketones instead of hydroxyenamines (Breslow intermediates).

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