The dynamics of chemical reaction networks often takes place on widely differing time scales--from the order of nanoseconds to the order of several days. This is particularly true for gene regulatory networks, which are modeled by chemical kinetics. Multiple time scales in mathematical models often lead to serious computational difficulties, such as numerical stiffness in the case of differenti...

the effect of mechanical activation on structural changes and kinetics of carbothermic reduction of hematite with graphite was studied in this research. hematite powder mixture with graphite (with stoichiometry ratio c/o=1) was milled for the time periods of zero to 50 hours, and the structural changes were studied using x ray diffraction (xrd). the effect of mechanical activation on the kineti...

the polarimetric entropy and the alpha angle are two important parameters for analyzing polarimetric synthetic aperture radar data. they demonstrate the degree of randomness in the polarization of the received signal and scattering mechanism of scatterers respectively. recently, there has been an increasing interest in compact polarimetry due to its advantages in comparison with full polarimetr...

The firefly luciferase complementation assay is widely used as a bioluminescent reporter technology to detect protein-protein interactions in vitro, in cellulo, and in vivo. Upon the interaction of a protein pair, complemented firefly luciferase emits light through the adenylation and oxidation of its substrate, luciferin. Although it has been suggested that kinetics of light production in the ...

This review summarizes findings from multiple complementary quantitative investigations of adhesion by classical cadherins. The systems investigated range from single molecules to cells, and the approaches used quantify the kinetics, energetics and mechanical strengths of cadherin bonds. The cumulative results demonstrate that cadherins adhere via a multistage binding mechanism that involves mu...

Sucrose is applied as an efficient catalyst for the three-component reaction consisting of aromatic aldehydes, malononitrile and resorcinol in a mixture of water and ethanol media as green solvents. The advantages of this method are excellent yeild, inexpensive catalyst and more environmentally friendly. Mechanistic insight into the synthesis of 2-amino-4H-chromene included spectral kinetics ap...

In this work, experimental kinetics data of methane hydrate decomposition at temperatures ranging from 272.15 to 276.15 K and at pressures ranging from 10 to 30 bars were modeled by using chemical affinity. This model proposed a macroscopic model which is independent of any intermediate mechanism like heat or mass transfer. The results show there is good agreement with experimental data. Al...

The design of Medium Access Control (MAC) protocols for multi-hop ad hoc networks is challenging as each network entity has only a local view of the network. Consequently, efficient, decentralized, MAC protocols are needed. In this paper, we demonstrate that a protocol based on a local backoff mechanism can globally organize the transmissions in a network. Moreover, we show that such a protocol...