The kinetics of film growth of hydrates of methane, ethane, and methane-ethane mixtures were studied by exposing a single gas bubble to water. The morphologies, lateral growth rates, and thicknesses of the hydrate films were measured for various gas compositions and degrees of subcooling. A variety of hydrate film textures was revealed. The kinetics of two-dimensional film growth was inferred f...

Laboratory based research on the physical properties of gas hydrate hosting sediment matrix was carried out on the non-pressurized hydrate-bearing sediment samples from the Chinese Guangzhou Marine Geological Survey 2 (GMGS2) drilling expedition in the Pearl River Mouth (PRM) basin. Measurements of index properties, surface characteristics, and thermal and mechanical properties were performed o...

[1] The interaction among water molecules, guest gas molecules, salts, and mineral particles determines the nucleation and growth behavior of gas hydrates in natural sediments. Hydrate of tetrahydrofuran (THF) has long been used for laboratory studies of gas hydrate-bearing sediments to provide close control on hydrate concentrations and to overcome the long formation history of methane hydrate...

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Scientific and technological innovations are needed to realize effective production of natural gas hydrates. Whereas global estimates of natural gas hydrate reservoirs are vast, accumulations vary greatly in nature and form. Suboceanic deposits vary from disperse concentrations residing at low saturations in the pore space of unconsolidated sediments with sand-sized particles to higher concentr...

Methane hydrate (MH) is a new energy resource in the 21 century. But the dissociation of MH from sediments during the MH exploration or oil/gas exploration under a hydrate layer accompanied by the softening of soils and formation of excess pore gas pressure may lead to ground failures and environmental disasters. In this study, experiments on modeling the weakening and failure of the sediment b...

This paper reports the three-phase (gas + liquid + hydrate) equilibrium pressure versus temperature data for a (O3 + O2 + CO2 + H2O) system for developing the hydrate-based technology to preserve ozone, a chemically unstable substance, for various industrial, medical and consumer uses. These data cover the temperature range from 272 K to 277 K, corresponding to pressures from 1.6 MPa to 3.1 MPa...

This paper reports the three-phase (gas + liquid + hydrate) equilibrium pressure versus temperature data for a (O3 + O2 + CO2 + H2O) system for developing the hydrate-based technology to preserve ozone, a chemically unstable substance, for various industrial, medical and consumer uses. These data cover the temperature range from 272 K to 277 K, corresponding to pressures from 1.6 MPa to 3.1 MPa...

Natural gas hydrate accumulations were confirmed in the Dongsha Area of the South China Sea by the Guangzhou Marine Geological Survey 2 (GMGS2) scientific drilling expedition in 2013. The drilling sites of GMGS2-01, -04, -05, -07, -08, -09, -11, -12, and -16 verified the existence of a hydrate-bearing layer. In this work gas production behavior was evaluated at GMGS2-8 by numerical simulation. ...

We study diffusive transport of aqueous methane in sea sediments, which is important for formation of methane hydrate and gas deposits and has even been claimed to be principal methane transport mechanism for some geological systems. The isothermal diffusion law (Fick's law), D X = − ∇ J , which is employed in the literature for investigations on methane hydrate, is shown to significantly devia...