Surface enhanced Raman scattering (SERS) and molecular fluorescence are used to probe the structure of a methylene blue monolayer adsorbed onto a sulfur-modified polycrystalline gold electrode. Changes in the wavelength of fluorescence for methylene blue on the gold electrode as compared to dilute solution indicate that the dye molecules' state of aggregation and electronic structure have been ...

Recent work has demonstrated nanopatterning of gold, using a Focussed Ion Beam, and similarly, nanotemplating gold, for direct protein attachment, useful for alternative sensing techniques. The impedance changes due to myoglobin capture by antimyoglobin immobilised on gold, have been measured, in a 3 electrode electrochemical cell. The impedance changes reach an end-point level after 15-20 minu...

Seed-mediated growth of gold nanoparticles on glassy carbon (GC) surfaces was developed. The field emission scanning electron microscopy (FE-SEM) and electrochemical characterization confirmed the effective attachment of gold nanoparticles on GC surface with such a wet-chemical method. The as-prepared gold nanoparticles attached glassy carbon electrode (Au/GCE) presented excellent catalytic abi...

Carboxylated single-walled carbon nanotubes (SWCNT) chemically assembled on gold substrate was employed as netlike electrode to investigate the charge-transfer process and electrode process kinetics using uric acid as an example. The electrochemical behavior of uric acid in carboxylated SWCNT system was investigated using cyclic voltammetry, chronoamperometry, and single potential time-based te...

In this paper, multi-wall carbon nanotubes (MWCNTs), gold nanoparticles (GNp) and glucose oxidase (GOD) was developed for the specific detection of glucose. MWCNTs were chemically modified with the H2SO4–HNO3 pretreatment to introduce carboxyl groups which were used to interact with the amino groups of poly(allylamine) (PAA) and cysteamine via 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide/N-hy...

In this paper, multi-wall carbon nanotubes (MWCNTs), gold nanoparticles (GNp) and glucose oxidase (GOD) was developed for the specific detection of glucose. MWCNTs were chemically modified with the H2SO4–HNO3 pretreatment to introduce carboxyl groups which were used to interact with the amino groups of poly(allylamine) (PAA) and cysteamine via 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide/N-hy...

a Nano & Micro Engineering Laboratory, Department of Materials Science & Engineering, University of Idaho, Moscow, ID 83844, USA b Department of Plastic Engineering, University of Massachusetts, Lowell, MA 01854, USA c Department of Mechanical & Aerospace Engineering, University of California, Los Angeles, CA 90095, USA d Electronics Photonics Laboratory, The Aerospace Corporation, El Segundo, ...

We have measured the conductance of single peptides covalently bonded to two Au electrodes via S-Au bonds by repeatedly forming a large number of molecular junctions. The conductance decreases exponentially with the peptide length, with a decay constant of beta = 0.9 +/- 0.1 A-1, suggesting that tunneling is the mechanism of electron transport in the peptides. The conductance of the peptides is...