The Journal of Physical Chemistry B is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Article Photoelectrochemistry of Films of Quantum Size Lead Sulfide Particles Incorporated in Self-Assembled Monolayers on Gold Shuichiro Ogawa, Kai Hu, Fu-Ren F. Fan, and Allen J. Bard J. Phys. Chem. B, 1997, 101 (29), 5707-5711 • DOI: 10.1021/jp970737j Downloaded...

Transition-metal alkane-thiolates (i.e., organic salts with formula Me(SR)x, where R is a linear aliphatic hydrocarbon group, –CnH2n+1) undergo a thermolysis reaction at moderately low temperatures (close to 200 °C), which produces metal atoms or metal sulfide species and an organic by-product, disulfide (RSSR) or thioether (RSR) molecules, respectively. Alkane-thiolates are non-polar chemical ...

Sulfur speciation was determined in real time in salt marsh microbial mats, subtidal sediments and hydrothermal vent diffuse flow waters using solid state gold-amalgam voltammetric microelectrodes. Chemical species were measured in situ without any sample manipulation or processing. The partially oxidized sulfur species detected were polysulfides, thiosulfate, elemental sulfur and tetrathionate...

Spontaneous elongation from nanorod to nanowire in the presence of an amine is reported for nanocrystals of cadmium sulfide and silver sulfide (cation exchanged from CdS). Elongation occurs instantaneously where the final aspect ratio is a controllable multiple of the original nanorod length. Transmission electron microscopy (TEM) analysis reveals the influential factors on the attachment proce...

At the orogenic gold deposits of Yana–Kolyma metallogenic belt (northeast Russia) both Au–quartz-sulfide mineralization with native and disseminated sulfide invisible Au developed. The textural mineralogical-geochemical features, isotope-geochemical characteristics gold-bearing sulfides from proximal metasomatites, possible forms occurrence in pyrite arsenopyrite have been studied using electro...

The synthesis, properties and reactivity of group 11 organotin sulfide clusters [(R(1)Sn)4(SnCl)2(MPPh3)2S8] (M = Cu, Ag), [(R(3)Sn)10Ag10S20], and [(R(1,3)Sn)2(AuPPh3)2S4] with covalently bound, carbonyl or hydrazine-terminated ligands R(1) = CMe2CH2C(Me)O or R(3) = CMe2CH2C(Me)NNH2 are reported.

Using ab initio methods, we investigate the structural evolution of a family of gold-sulfide cluster anions (Au(m)S(n)(-)). We show that this family of clusters exhibits simple size-evolution rules and novel hollow polyhedron structures. The highly stable Au(m)S(n)(-) species such as Au(6)S(4)(-), Au(9)S(5)(-), Au(9)S(6)(-), Au(10)S(6)(-), Au(11)S(6)(-), Au(12)S(8)(-), and Au(13)S(8)(-) detecte...

Hybrid nanostructures are interesting materials for numerous applications in chemistry, physics, and biology, due to their novel properties and multiple functionalities. Here, we present a synthesis of metal–semiconductor hybrid nanostructures composed of nontoxic I-III-VI semiconductor nanoparticles and gold. Copper indium sulfide selenide (CuInSSe) nanocrystals with zinc blende structure and ...

the term biomining have been coined to refer to the use of microorganisms in mining processes as in the biooxidation of refractory gold minerals. the biooxidation of refractory gold ores presents similar characteristics when compared with roasting and pressure oxidation. almost without exception, microbial extraction procedures are more environmentally friendly. the isolated bacteria in this st...