We investigate electron and phonon transport through edge disordered zigzag graphene nanoribbons based on the same methodological tool of nonequilibrium Green functions. We show that edge disorder dramatically reduces phonon thermal transport while being only weakly detrimental to electronic conduction. The behavior of the electronic and phononic elastic mean free paths points to the possibilit...

We study the electronic structure of chiral and achiral graphene nanoribbons with symmetric edges, including curvature and spin-orbit effects. Curved ribbons show spin-split bands, whereas flat ribbons present spin-degenerate bands. We show that this effect is due to the breaking of spatial inversion symmetry in curved graphene nanoribbons, while flat ribbons with symmetric edges possess an inv...

The quantum corrections to the energies of the point optical phonon modes Kohn anomalies in graphene nanoribbons NRs are investigated. We show theoretically that the longitudinal optical LO modes undergo a Kohn anomaly effect, while the transverse optical TO modes do not. In relation to Raman spectroscopy, we show that the longitudinal optical modes are not Raman active near the zigzag edge, wh...

Chemical functionalization is one of the most powerful and widely used strategies to control the properties of nanomaterials, particularly in the field of graphene. However, the ill-defined structure of the present functionalized graphene inhibits atomically precise structural characterization and structure-correlated property modulation. Here we present a general edge chlorination protocol for...

Suspended graphene nanoribbons formed during current annealing of suspended graphene flakes have been investigated experimentally. Transport measurements show the opening of a transport gap around charge neutrality due to the formation of "Coulomb islands", coexisting with quantum Hall conductance plateaus appearing at moderate values of the magnetic field B. Upon increasing B, the transport ga...

We report on the possibility for a spin-valve effect driven by edge defect engineering of zigzag graphene nanoribbons. Based on a mean-field spin-unrestricted Hubbard model, electronic band structures and conductance profiles are derived, using a self-consistent scheme to include gate-induced charge density. The use of an external gate is found to trigger a semiconductor-metal transition in cle...

We have used molecular dynamics to calculate the thermal conductivity of symmetric and asymmetric graphene nanoribbons (GNRs) of several nanometers in size (up to approximately 4 nm wide and approximately 10 nm long). For symmetric nanoribbons, the calculated thermal conductivity (e.g., approximately 2000 W/m-K at 400 K for a 1.5 nm x 5.7 nm zigzag GNR) is on the similar order of magnitude of t...