Graphite intercalation compounds, where some atom or molecule is inserted between the carbon layers of the host graphite, are attractive materials for charge storage. In commercial, rechargeable lithium ion batteries, for instance, the graphite anode intercalates and de-intercalates lithium as the battery is cycled [1]. In this work we present our in situ scanning transmission electron microsco...

In this work, the reduced graphene nanosheets were synthesized from pre-exfoliated graphite flakes. The pristine graphite flakes were firstly pre-exfoliated to graphite nanoplatelets in the presence of acetic acid. The obtained graphite nanoplatelets were treated by Hummer’s method to produce graphite oxide sheets and were finally exfoliated to graphene nanosheets by ultrasonication and reducti...

Different bulk structures of graphite oxide were systematically investigated using density functional theory (DFT). Our model consisted of a hexagonal in-plane structure of graphene with hydroxyl and epoxide groups, and different oxidation levels and water content. The graphitic AB stacking order was stable in anhydrous graphite oxide, independent of oxidation levels. The hydrogen bonding inter...

Fine-grained isotropic graphite is the material of choice for the production target and the beam catchers at the planned Super-FRS fragment separator at FAIR. Heavyion irradiation studies of graphite are needed, as radiation damage will ultimately limit the lifetime of these components. Polycrystalline graphite and highly-oriented pyrolytic graphite (HOPG) were irradiated with energetic ions an...

Single-walled carbon nanotubes (SWNTs) [1] is now recognized as the most fascinating material of so-called nano-technology in this century. Despite the expectation of future applications, it is still difficult to obtain large amount of pure SWNTs, because the generation process is still not clear. It is well known that transition metals such as La, Y and Sc can be encapsulated inside the fuller...

Boron strongly modifies electronic and diffusion properties of graphite. We report the first ab initio study of boron interaction with the point defects in graphite, which includes structures, thermodynamics, and diffusion. A number of possible diffusion mechanisms of boron in graphite are suggested. We conclude that boron diffuses in graphite by a kick-out mechanism. This mechanism explains th...

7 Carbon-14 (C-14) is a key radionuclide in the assessment of a geological 8 disposal facility (GDF) for radioactive waste. In the UK a significant proportion of 9 the national C-14 inventory is associated with reactor core graphite generated by 10 the decommissioning of the UK’s Magnox and AGR reactors. 11 There are a number of uncertainties associated with the fate and transport of 12 C-14 in...

Heat flux gauges are one of the devices that are used to determine the heat loads to which high-speed aerospace structures are subjected during flight. Prior to installation, these gauges are calibrated. The calibration system must be well understood if the heat flux gauges are to provide useful data during flight tests. A pseudo three-dimensional model of the radiant heat flux gauge calibratio...

The article reports about electric field-induced alignment of the carbon nanoparticles embedded in epoxy matrix. Optical microscopy was performed to consider the effect of the electric field magnitude and configuration, filler morphology, and aspect ratio on alignment process. Characteristic time of aligned network formation was compared with modeling predictions. Carbon nanotube and graphite n...

Graphite is an excellent material for bipolar plates used in Proton Exchange Membrane (PEM) fuel cell due to its great chemical resistance, but the brittle nature makes it difficult to manufacture. Selective Laser Sintering (SLS) based on layer-by-layer manufacturing technology can fabricate graphite bipolar plates with complex gas flow channels. To improve the performance of bipolar plates inc...