A new model of Li intercalation into rutile and anatase structured titania has been developed from first principles calculations. The model includes both thermodynamic and kinetic effects and explains the observed differences in intercalation behavior and their temperature dependence. The important role of strong local deformations of the lattice and elastic screening of interlithium interactio...

In the present overview, we describe the bases of intercalation of small molecules (cationic and polar neutral compounds) in DNA. We briefly describe the importance of DNA structure and principles of intercalation. Selected syntheses, possibilities and applications are shown to exemplify the importance, drawbacks and challenges in this pertinent, new, and exciting research area. Additionally, s...

Two novel coordination compounds of half-sandwiched ruthenium(II) containing 2-(5-fluorouracil)-yl-N-(pyridyl)-acetamide were synthesized, and their intercalation binding modes with calf thymus DNA were revealed by hyperchromism of ultraviolet-visible spectroscopy; the binding constants were determined according to a Langmuir adsorption equation that was deduced on the base of careful cyclic vo...

Layered intercalation compounds NaxMnO2 (x 5 0.7 and 0.91) nanoflakes have been prepared directly through wet electrochemical process with Na ions intercalated into MnO2 interlayers spontaneously. The as-prepared NaxMnO2 nanoflake based supercapacitors exhibit faster ionic diffusion with enhanced redox peaks, tenfold-higher energy densities up to 110 Wh?kg and higher capacitances over 1000 F?g ...

Angle-resolved photoemission spectroscopy and Auger electron spectroscopy have been applied to study the intercalation process of silver underneath a monolayer of graphite (MG) on Ni(111). The room-temperature deposition of silver on top of MG/Ni(111) system leads to the islands-like growth of Ag on top of the MG. Annealing of the ”as-deposited” system at temperature of 350450◦ C results in the...

In this article, we present a large-area synthesis of carbon microtubes (CMTs) with internal diameters of ∼1.5 μm and wall thicknesses on the order of 50 nm and their lithium ion intercalation and deintercalation properties for the first time. The results show that CMTs exhibit a good capacity retention of 443 mAh g-1 after 20 cycles, higher than the theoretical capacity of graphite and ∼1.5 ti...

The development of graphene electronic devices produced by industry relies on efficient control of heat transfer from the graphene sheet to its environment. In nanoscale devices, heat is one of the major obstacles to the operation of such devices at high frequencies. Here we have studied the transport of hot carriers in epitaxial graphene sheets on 6H-SiC (0001) substrates with and without hydr...

High-power Na-ion batteries have tremendous potential in various large-scale applications. However, conventional charge storage through ion intercalation or double-layer formation cannot satisfy the requirements of such applications owing to the slow kinetics of ion intercalation and the small capacitance of the double layer. The present work demonstrates that the pseudocapacitance of the nanos...

Intercalation pseudocapacitive Li(+) storage has been recognized recently in metal oxide materials, wherein Li(+) intercalation into the lattice is not solid-state diffusion-limited. This may bridge the performance gap between electrochemical capacitors and battery materials. To date, only a few materials with desired crystal structure and with well-defined nanoarchitectures have been found to ...

Intercalation products based on ionic exchange reaction between cationic dye methylene blue and Na-montmorillonite were prepared. Montmorillonite particles intercalated with methylene blue were characterized using X-ray diffraction, infrared spectroscopy, elemental and thermo-gravimetric analysis. The results showed that intercalation of dye molecules within the interlayer spaces of montmorillo...