نتایج جستجو برای: isotherm study

تعداد نتایج: 3971559  

Journal: :Analytical biochemistry 2003
Peter Schuck

Analytical ultracentrifugation is one of the classical techniques for the study of protein interactions and protein self-association. Recent instrumental and computational developments have significantly enhanced this methodology. In this paper, new tools for the analysis of protein self-association by sedimentation velocity are developed, their statistical properties are examined, and consider...

2006
M. Shahedi S. Emami

right of first publication of such papers, in complete form; however, CSBE/SCGAB has no objections to publication, in condensed form, with credit to the Society and the author, in other publications prior to use in Society publications. Permission to publish a paper in full may be requested from the CSBE/SCGAB Secretary, PO Box 23101, RPO McGillivray, Winnipeg MB R3T 5S3 or contact bioeng@shaw....

Journal: :Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 2003
Kiyoharu Nakatani Hiroshi Kakizaki

Intraparticle mass transfer processes of Phenol Blue (PB) in single octadecylsilyl (ODS)-silica gel microparticles in acetonitrile-water were analyzed by microcapillary manipulation and microabsorption methods. An absorption maximum of PB, the sorption isotherm parameters, and the sorption rate in the microparticle system were highly dependent on the percentage of acetonitrile in solution. The ...

2017
Dennis Åsberg Marek Leśko Tomas Leek Jörgen Samuelsson Krzysztof Kaczmarski Torgny Fornstedt

ABSTRACT In electrostatic repulsive interaction chromatography, using a charged surface hybrid sorbent carrying positive charges can improve the peak shape of peptides in reversed-phase liquid chromatography (RP-LC), especially in overloaded conditions, compared with standard C18 sorbents. However, the positive surface charges can interact with anionic additives commonly used in peptide separat...

2004
F. Stoeckli

The present paper examines the adsorption of water by microporous carbons containing various amounts of surface oxygen an a smaller proportion of basic centres. The modelling of water adsorption for 293 and 310 K, using variable pore size distribution (PSD), confirms that the overall type IV isotherm is the sum of a type I isotherm associated with the specific interactions, and a typ V isotherm...

2007
H. Benaïssa

In the present work, the usefulness of almond peel as a sorbent material has been investigated for the removal of methylene blue from synthetic aqueous solutions in batch conditions. Isotherm of dye sorption was measured. The influence of different experimental parameters such as: almond peel mass, particles size, temperature, initial pH of solution and NaCl concentration on this isotherm was s...

2011
LIDIJA ĆURKOVIĆ ALENKA RASTOVĈAN-MIOĈ

The effect of temperature on the equilibrium sorption of Pb 2+ from aqueous solution onto a low-cost electric furnace slag was investigated. In this paper, two-parameter isotherm models namely the Langmuir and the Freundlich and three-parameter isotherm model namely Redlich–Peterson were applied to describe the isotherms and to calculate their constants. The best estimation of the parameters of...

2011
MEHDI VADI

The present work investigates the equilibrium adsorption of Chrysene on multi-walled carbon nanotubes at 293, 303 and 313°K, and determines the equilibrium adsorption isotherms and thermodynamic parameters (ΔG, ΔH and ΔS). The values of ΔH and ΔG suggested that the adsorption of Chrysene onto MWCNTs was endothermic and nonspontaneous.The experimental data were analyzed using Langmuir, Freundlic...

2000
Randall A. La Violette Joanne L. Budzien Frank H. Stillinger

We calculated the inherent structure of a model melt of zinc ~II! bromide over a wide range of densities. Stable, metastable, and unstable branches were obtained for the zero temperature pressure–volume isotherm of the inherent structure. The pressure–volume isotherm, the void distribution, and the structure factor were used to identify the spinodal, independent of any model equation of state. ...

Journal: :Journal of hazardous materials 2011
Ying Yao Bin Gao Mandu Inyang Andrew R Zimmerman Xinde Cao Pratap Pullammanappallil Liuyan Yang

Biochar converted from agricultural residues or other carbon-rich wastes may provide new methods and materials for environmental management, particularly with respect to carbon sequestration and contaminant remediation. In this study, laboratory experiments were conducted to investigate the removal of phosphate from aqueous solution by biochar derived from anaerobically digested sugar beet tail...

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