The crystallization kinetics of Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 were studied in an electrostatic levitation ~ESL! apparatus. The measured critical cooling rate is 1.75 K/s. Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 is the first bulk-metallic-glass-forming liquid that does not contain beryllium to be vitrified by purely radiative cooling in the ESL. Furthermore, the sluggish crystallization kinetics enable th...

Poly(ethylene terephthalate) (PET) is a semi–crystalline polymer that can be crystallized to different degrees heating from the amorphous state. Even when primary crystallization has been completed, secondary crystallization can take place with further annealing and modify the characteristics of the amorphous interlamellar phase. In this work we study the glass transition of highly crystallized...

The present study explores the temperature and time dependence of heterogeneous (HET) crystal nucleation in a lithium disilicate glass using the stochastic approach. In particular, a single lithium disilicate sample was repeatedly (284 runs) undercooled to 1173K in a PtRh-crucible and the crystallization onset time during an isothermal hold was detected in each run. The statistical distribution...

Experiments show high-speed spinning of many synthetic bers is accompanied by the partial crys-tallization of the initially amorphous melt. This crystallization is induced by some combination of the extensional ow, molecular orientation and extension, and temperature dependence. The crystallization of the material couples back to aaect the ber rheology, through a process of stress-hardening. Re...