Co3O4 is an attractive earth-abundant catalyst for CO oxidation, and its high catalytic activity has been attributed to Co cations surrounded by Co ions. Hence, the majority of efforts for enhancing the activity of Co3O4 have been focused on exposing more Co cations on the surface. Herein, we enhance the catalytic activity of Co3O4 by replacing the Co ions in the lattice with Cu. Polycrystallin...

The effect of nano Co3O4 addition on the superconducting properties of (Bi, Pb)-2223 system was studied. The samples were prepared by the acetate coprecipitation method. The Co3O4 with different sizes (10-30 nm and 30-50 nm) from x=0.00 to 0.05 was added to Bi1.6Pb0.4Sr2Ca2Cu3Oy(Co3O4)x. Phase analysis by XRD method, microstructural examination by SEM and dc electrical resistivity by four point...

A facile strategy for the design of porous supports was obtained by modifying sol-gel method followed wet impregnation technique. In this respect, herein, acidity γ-Al2O3 phase modulated adding basic MgO, La2O3 or ZnO promoters to form binary supported catalysts. The Ni and Co dispersion on associated with their tunable morphologies resulted in highly alumina-based physicochemical properties so...

A low cost, durable, and efficient electrocatalyst for oxygen reduction reactions (ORR) is essential for high-performance fuel cells. Here, we fabricated Co3O4 nanoparticles (NPs) anchored on N-doped mesoporous carbon nanofibers (Co3O4/NMCF) by electrospinning combined with the simple heat treatment. Within this composite, carbon nanofibers possess a mesoporous structure, contributed to obtain ...

Spectroscopic ellipsometry and atomic force microscope techniques were employed to analyze optical properties, microstructure and thickness of cobalt oxide thin films deposited on metal substrates by the sol-gel dipping method. The ellipsometric data were conveniently fitted, assuming a stratified structure for the deposited film, which consists of a sublayer native oxide that was coated with a...

Here we proposed a novel architectural design of a ternary MnO2-based electrode - a hierarchical Co3O4@Pt@MnO2 core-shell-shell structure, where the complemental features of the three key components (a well-defined Co3O4 nanowire array on the conductive Ti substrate, an ultrathin layer of small Pt nanoparticles, and a thin layer of MnO2 nanoflakes) are strategically combined into a single entit...

One-dimensional (1D) hierarchical porous nanofibers of Co3O4 possessing of (220) facets on the carbon matrix from human hair (H2@Co3O4) with 20-30 nm in width and 3-5 μm in length are prepared by a facile solvothermal and calcination approach. The well crystallized small Co3O4 particles with the diameter of about 8-12 nm were closely aggregated together in the nanofibers. Electrochemical analys...

Artificial photosynthesis is a very attractive and a desirable way to solve the rising energy demand. In order to harvest energy directly from sunlight catalyst for oxygen reduction and evolution reaction are at the core of key renewable-energy technologies including fuel cells and water splitting. Herein, tungsten oxide-reduced graphene oxide (WO3-rGO), cobalt oxidereduced graphene oxide (Co3O...

A series of novel hierarchical nanoporous microstructures have been synthesized through one-step chemical reduction of micron size Cu2O and Co3O4 particles. By controlling the reduction time, non-porous Cu2O microcubes sequentially transform to nanoporous Cu/Cu2O/Cu dented cubic composites and hollow eightling-like Cu microparticles. The mechanism involved in the complex structural evolution is...