The model and theoretical understanding of the Raman spectra in disordered and amorphous carbon are given. The nature of the G and D vibration modes in graphite is analyzed in terms of the resonant excitation of p states and the long-range polarizability of p bonding. Visible Raman data on disordered, amorphous, and diamondlike carbon are classified in a three-stage model to show the factors th...

Diamond-like carbon films form a critical protective layer on magnetic hard disks and their reading heads. The ultimate limit to storage density is the super-paramagnetic limit, where the thermal energy is able to overcome the coercive energy of the magnetic bit. Perpendicular recording should allow storage densities up to ;1 Tbityinch . This requires the read head to approach 2 closer to the m...

The Jahn-Teller effect used semi-theoretically to analyse UV-visible spectra of the diamond like-carbon films on Si substrates. By deconvolution of UV-visible absorption spectra of the typical films, different absorption lines found. For each sample, six lines which were related to V • by Jahn-Teller effect are distinguished. Our theoretical approach based on distortion of the V • as the conseq...

clicking here. colleagues, clients, or customers by , you can order high-quality copies for your If you wish to distribute this article to others here. following the guidelines can be obtained by Permission to republish or repurpose articles or portions of articles ): June 10, 2011 www.sciencemag.org (this infomation is current as of The following resources related to this article are availab...

A new material containing macroscopic quantities of onion-like carbon (OLC) particles is produced by heat treatment of ultra-disperse diamond (UDD) powder (2-6 nm). Annealing products (characterized by high-resolution electron microscopy) are presented by: (a) quasi-spherical particles with closed concentric graphite shells, (b ) polyhedron particles with closed shells, (c) elongated particles ...

K. Jarolimek,1,2 R. A. de Groot,2 G. A. de Wijs,2 and M. Zeman1 1DIMES, Delft University of Technology, Feldmannweg 17, 2600 GB Delft, The Netherlands 2Electronic Structure of Materials, Institute for Molecules and Materials, Faculty of Science, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands Received 23 May 2008; revised manuscript received 9 February 2009; p...

Thin films, used in various applications and devices, must strongly adhere to their substrates. Due to various processing and storage environments that devices can be exposed to, water may be introduced into the system. If residual stresses are present in a thin film, delamination propagation can be driven by water without the assistance of an externally applied mechanical force. It is extremel...

Bamboo-like carbon nanotubes are members of the carbon nanotubes (CNTs) family, whose structure is made up of separated hollow compartments and bamboo knots. Due to the peculiar structure of the CNTs species, the growth mechanism and related features have been widely investigated. Bamboo-like carbon nanotubes are widely applied in several fields, such as sensors, adsorbents, catalysts, and lith...

Nitrogenated diamond-like carbon (N:DLC) thin films fabricated with filtered cathodic vacuum arc (FCVA) can have a high sp content. Their superior electrochemical properties such as wide potential window and low background current make them a more promising electrode material than conventional carbon-based electrodes. The N:DLC films give pronounced signals for tracing analysis of Pb, Cu and Hg...