A novel and environmentally benign approach is described to combine reactions and separations, using simultaneously ionic liquids (ILs) and supercritical carbon dioxide (SCCO2). The novel approach is based on the phenomenon that two (partially) immiscible liquid phases upon pressurization with CO2 is able to force to form one homogeneous fluid phase. The homogeneous phase allows reactions to be...

In this research, hybrid materials based on poly(methyl methacrylate) and silica were synthesized via sol±gel process. Their glass transition behavior was investigated by differential scanning calorimeter. In DSC measurement, 1808C heat-treated hybrid materials exhibited higher miscibility as compared to untreated materials. Relationship between miscibility variation of hybrid materials and hea...

Abstract The Water Alternating Gas (WAG) process is a cyclic of injecting alternating water followed by gas. main purpose WAG injection to improve both macroscopic and microscopic sweep efficiency, maintaining nearly initial high pressure, slow down the gas breakthrough reduced oil viscosity. also decreases residual saturation resulted from flow three phases effects associated with relative per...

In Japan, the refrigerant used in room air-conditioners has been changed from HCFC-22 (R-22) to R-410A, a blend of HFC-32 and HFC-125 (50/50 vt%), in order to protect the ozone layer. Generally, the miscibility between the refrigerant and refrigeration oil must be assured, because the oil needs to return to the compressor from the refrigeration cycle and lubricate the sliding parts. Alternative...

Publication date: 2014 Document Version Early version, also known as pre-print Citation for published version (APA): Mortensen, K. (2014). Characterization of Polymer Blends: Miscibility, Morphology and Interfaces. In Characterization of Polymer Blends and Block Copolymers by Neutron Scattering: Miscibility and Nanoscale Morphology (Wiely-VCH Verlag ed., Chapter Chapter 7, pp. 237-268). Wiley-VCH.

The viscosity behavior of aqueous mixtures formed by a polyelectrolyte (A) and a neutral polymer (B), such as chitosan/poly(vinyl alcohol) (Ch/PVA) and microcrystalline chitosan/poly(vinyl alcohol) (MCCh/PVA), have been investigated at 25 °C. The intrinsic viscosity and the viscosity interaction parameter of each polymer in 0.1 mol·dm-3 CH3COOH/0.2 mol·dm-3 NaCl solution as well as the ternary ...

In this paper, we report the calculated phase diagrams of V-Nb, V-Ta, and Nb-Ta alloys computed by combining the total energies of 40–50 configurations for each system (obtained using density functional theory) with the cluster expansion and Monte Carlo techniques. For V-Nb alloys, the phase diagram computed with conventional cluster expansion shows a miscibility gap with consolute temperature ...

Abstract Since the influence of carbon dioxide (CO 2 ) on dynamic interfacial tension crude oil and aqueous solutions at elevated temperatures pressures is an important issue, this investigation aimed to measure IFT oil/water, CO , carbonated water. The measured values reveal that IFTs oil/CO are decreased through first interval, while a gradual continuous reduction in obtained second interval....